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Cluster Core-Level Binding-Energy Shifts: The Role of Lattice Strain
Open accessAbstract
Our combined experimental and theoretical analysis of the shifts, with particle size, of core-level binding energies (BE's) of metal nanoparticles on insulating supports, shows that these shifts have an important initial state contribution arising, in large part, because of lattice strain. This contribution of BE shifts has not been recognized previously. Lattice strain changes the chemical bonding between the metal atoms and this change induces BE shifts.
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Citations
Cites
Electronic structure of supported small metal clusters
Mason, M. G. (1983) · Physical Review B · doi:10.1103/physrevb.27.748 · Cited by 936
Hüfner, S. (1995) · Springer Series in Solid-State Sciences · doi:10.1007/978-3-662-03150-6 · Cited by 854
Cited by
Zhou, W. P., Lewera, A., Larsen, R., Masel, R. I., Bagus, P. S., & Wieckowski, A. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp061690h · Cited by 498
Self-citationPhotochemistry on Metal Nanoparticles
Watanabe, K., Menzel, D., Nilius, N., & Freund, H.-J. (2006) · Chemical Reviews · doi:10.1021/cr050167g · Cited by 486
Self-citationLiu, G., Zhou, W., Ji, Y., Chen, B., Fu, G., Yun, Q., Chen, S., Lin, Y., Yin, P.-F., Cui, X., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05856 · Cited by 269
Ag nanoparticles on highly ordered pyrolytic graphite (HOPG) surfaces studied using STM and XPS
Lopez-Salido, I., Lim, D. C., & Kim, Y. D. (2005) · Surface Science · doi:10.1016/j.susc.2005.05.021 · Cited by 252
Metadata
- Authors
- Richter, B., Kuhlenbeck, H., Freund, H.-J., & Bagus, P. S.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2004-07-08
- Volume
- 93
- Issue
- 2
- Pages
- 026805-026805
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2006851554
- Cited by
- 199
- References
- 2
- FWCI
- 3.51
- Type
- journal article
- Language
- en
- Open access
- green
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- Richter, B., Kuhlenbeck, H., Freund, H.-J., & Bagus, P. S. (2004). Cluster Core-Level Binding-Energy Shifts: The Role of Lattice Strain. Physical Review Letters. https://doi.org/10.1103/physrevlett.93.026805
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