The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Direct Observation of Hydrogen Adsorption Sites and Nanocage Formation in Metal-Organic Frameworks
Open accessAbstract
The hydrogen adsorption sites in MOF5 were determined using neutron powder diffraction along with first-principles calculations. The metal-oxide cluster is primarily responsible for the adsorption while the organic linker plays only a secondary role. Equally important, at low temperatures and high-concentration, molecules form unique interlinked high-symmetry nanoclusters with intermolecular distances as small as 3.0 Angstrom and H(2) uptake as high as 11 wt %. These results hold the key to optimizing metal-organic framework (MOF) materials for hydrogen storage applications and also suggest that MOFs can be used as templates to create artificial interlinked hydrogen nanocages with novel properties.
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Cites
Materials for hydrogen storage
Züttel, A. (2003) · Materials Today · doi:10.1016/s1369-7021(03)00922-2 · Cited by 2,216
Cited by
Wu, H., Chua, Y. S., Krungleviciute, V., Tyagi, M., Chen, P., Yildirim, T., & Zhou, W. (2013) · Journal of the American Chemical Society · doi:10.1021/ja404514r · Cited by 1,457
Self-citationHan, S. S., Mendoza-Cortés, J. L., & Goddard III, W. A. (2009) · Chemical Society Reviews · doi:10.1039/b802430h · Cited by 594
Metadata
- Authors
- Yildirim, T., & Hartman, M.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2005-11-16
- Volume
- 95
- Issue
- 21
- Pages
- 215504-215504
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2145624705
- Cited by
- 282
- References
- 1
- FWCI
- 17.38
- Type
- journal article
- Language
- en
- Open access
- green
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- Yildirim, T., & Hartman, M. (2005). Direct Observation of Hydrogen Adsorption Sites and Nanocage Formation in Metal-Organic Frameworks. Physical Review Letters. https://doi.org/10.1103/physrevlett.95.215504
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