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Probing the Nanohydrodynamics at Liquid-Solid Interfaces Using Thermal Motion
Open accessAbstract
We report on a new method to characterize nanohydrodynamic properties at the liquid-solid interface relying solely on the measurement of the thermal motion of confined colloids. This equilibrium measurement of surface properties--equivalent in spirit to the passive microrheology technique used for bulk properties--is able to achieve nanometric resolution on the slip length measurement. Exploring the "zero shear rate" limit, it rules out shear rate threshold to slip effects and extends the range over which slip lengths are shown to be flow independent. Avoiding the nucleation of gas pockets (nanobubbles) through external forcing, it validates the theoretical picture for intrinsic liquid-solid interfaces, reporting nanometric slip lengths (b=18+/-5 nm) only in nonwetting situations, opening the route to quantitative study on more complex surfaces with combined effects of nonwettability and roughness.
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Cites
The drainage of thin liquid films between solid surfaces
Chan, D. Y. C., & Horn, R. G. (1985) · The Journal of Chemical Physics · doi:10.1063/1.449693 · Cited by 762
Cited by
Bazant, M. Z., Kilic, M. S., Storey, B. D., & Ajdari, A. (2009) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2009.10.001 · Cited by 916
Interfacial Water at Hydrophobic and Hydrophilic Surfaces: Slip, Viscosity, and Diffusion
Sendner, C., Horinek, D., Bocquet, L., & Netz, R. R. (2009) · Langmuir · doi:10.1021/la901314b · Cited by 567
Self-citationWater Slippage versus Contact Angle: A Quasiuniversal Relationship
Huang, D. M., Sendner, C., Horinek, D., Netz, R. R., & Bocquet, L. (2008) · Physical Review Letters · doi:10.1103/physrevlett.101.226101 · Cited by 527
Self-citationOrigins of hydration lubrication
Ma, L., Gaisinskaya-Kipnis, A., Kampf, N., & Klein, J. (2015) · Nature Communications · doi:10.1038/ncomms7060 · Cited by 390
Metadata
- Authors
- Joly, L., Ybert, C., & Bocquet, L.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2006-02-02
- Volume
- 96
- Issue
- 4
- Pages
- 046101-046101
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2030872016
- Cited by
- 185
- References
- 1
- FWCI
- 10.24
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Joly, L., Ybert, C., & Bocquet, L. (2006). Probing the Nanohydrodynamics at Liquid-Solid Interfaces Using Thermal Motion. Physical Review Letters. https://doi.org/10.1103/physrevlett.96.046101
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