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How Water Meets a Hydrophobic Surface
Abstract
Synchrotron x-ray reflectivity measurements of the interface between water and methyl-terminated octadecylsilane monolayers with stable contact angle >100 degrees conclusively show a depletion layer, whether or not the water is degassed. The thickness is of order one water molecule: 2-4 Angstrom with electron density <40% that of bulk water. Considerations of coherent and incoherent averaging of lateral inhomogeneities show that the data cannot be explained by "nanobubbles." When the contact angle is lower, unstable in time, or when monolayers fail to be sufficiently smooth over the footprint of the x-ray beam, there is no recognizable depletion.
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Citations
Cites
Thermal Conductance of Hydrophilic and Hydrophobic Interfaces
Ge, Z., Cahill, D. G., & Braun, P. V. (2006) · Physical Review Letters · doi:10.1103/physrevlett.96.186101 · Cited by 455
Cited by
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Joseph, S., & Aluru, N. R. (2008) · Nano Letters · doi:10.1021/nl072385q · Cited by 834
Long range interactions in nanoscale science
French, R. H., Parsegian, V. A., Podgornik, R., Rajter, R. F., Jagota, A., Luo, J., Asthagiri, D., Chaudhury, M. K., Chiang, Y.-M., Granick, S., et al. (2010) · Reviews of Modern Physics · doi:10.1103/revmodphys.82.1887 · Cited by 441
Self-citationGodawat, R., Jamadagni, S. N., & Garde, S. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0902778106 · Cited by 357
Developing a General Interaction Potential for Hydrophobic and Hydrophilic Interactions
Donaldson, S. H., Røyne, A., Kristiansen, K., Rapp, M. V., Das, S., Gebbie, M. A., Lee, D. W., Stock, P., Valtiner, M., & Israelachvili, J. (2015) · Langmuir · doi:10.1021/la502115g · Cited by 255
Metadata
- Authors
- Poynor, A., Hong, L., Robinson, I. K., Granick, S., Zhang, Z., & Fenter, P. A.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2006-12-27
- Volume
- 97
- Issue
- 26
- Pages
- 266101-266101
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2167678601
- Cited by
- 314
- References
- 1
- FWCI
- 14.26
- Type
- journal article
- Language
- en
- Open access
- closed
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- Poynor, A., Hong, L., Robinson, I. K., Granick, S., Zhang, Z., & Fenter, P. A. (2006). How Water Meets a Hydrophobic Surface. Physical Review Letters. https://doi.org/10.1103/physrevlett.97.266101
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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