The DOI matches its Crossref record.
Role of Intermolecular Coupling in the Photophysics of Disordered Organic Semiconductors: Aggregate Emission in Regioregular Polythiophene
Open accessAbstract
We address the role of excitonic coupling on the nature of photoexcitations in the conjugated polymer regioregular poly(3-hexylthiophene). By means of temperature-dependent absorption and photoluminescence spectroscopy, we show that optical emission is overwhelmingly dominated by weakly coupled H aggregates. The relative absorbance of the 0-0 and 0-1 vibronic peaks provides a powerfully simple means to extract the magnitude of the intermolecular coupling energy, of approximately 5 and 30 meV for films spun from isodurene and chloroform solutions, respectively.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Structural control of mixed ionic and electronic transport in conducting polymers
Rivnay, J., Inal, S., Collins, B. A., Sessolo, M., Stavrinidou, E., Strakosas, X., Tassone, C., Delongchamp, D. M., & Malliaras, G. G. (2016) · Nature Communications · doi:10.1038/ncomms11287 · Cited by 939
Light Harvesting for Organic Photovoltaics
Hedley, G. J., Ruseckas, A., & Samuel, I. D. W. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00215 · Cited by 580
Koch, F. P. V., Rivnay, J., Foster, S., Müller, C., Downing, J. M., Buchaca-Domingo, E., Westacott, P., Yu, L., Yuan, M., Baklar, M., et al. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.07.009 · Cited by 337
Self-citationThe Structure and Dynamics of Molecular Excitons
Bardeen, C. J. (2014) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-040513-103654 · Cited by 264
Switching between H- and J-type electronic coupling in single conjugated polymer aggregates
Eder, T., Stangl, T., Gmelch, M., Remmerssen, K., Laux, D., Höger, S., Lupton, J. M., & Vogelsang, J. (2017) · Nature Communications · doi:10.1038/s41467-017-01773-0 · Cited by 135
Metadata
- Authors
- Clark, J., Silva, C., Friend, R. H., & Spano, F. C.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2007-05-17
- Volume
- 98
- Issue
- 20
- Pages
- 206406-206406
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W1972333973
- Cited by
- 962
- References
- 0
- FWCI
- 27.72
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Role of Intermolecular Coupling in the Photophysics of Disordered Organic Semiconductors: Aggregate Emission in Regioregular Polythiophene. https://app.cochat.ai/papers/10.1103/physrevlett.98.206406
- The paper
- Clark, J., Silva, C., Friend, R. H., & Spano, F. C. (2007). Role of Intermolecular Coupling in the Photophysics of Disordered Organic Semiconductors: Aggregate Emission in Regioregular Polythiophene. Physical Review Letters. https://doi.org/10.1103/physrevlett.98.206406
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
