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Measuring Thermodynamic Length

Open access
Crooks, Gavin E.·2007·Physical Review Letters

Abstract

Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It is also connected to the Jensen-Shannon divergence, Fisher information, and Rao's entropy differential metric. Therefore, thermodynamic length is of central interest in understanding matter out of equilibrium. In this Letter, we will consider how to define thermodynamic length for a small system described by equilibrium statistical mechanics and how to measure thermodynamic length within a computer simulation. Surprisingly, Bennett's classic acceptance ratio method for measuring free energy differences also measures thermodynamic length.

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Metadata

Authors
Crooks, G. E.
Venue
Physical Review Letters
Published
2007-09-07
Volume
99
Issue
10
Pages
100602-100602
ISSN
  • 0031-9007 (ISSN-L)
  • 1079-7114
OpenAlex
W2047676282
Cited by
424
References
0
FWCI
3.71
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Measuring Thermodynamic Length. https://app.cochat.ai/papers/10.1103/physrevlett.99.100602
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Crooks, G. E. (2007). Measuring Thermodynamic Length. Physical Review Letters. https://doi.org/10.1103/physrevlett.99.100602

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