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Bond valence vs bond length in O...O hydrogen bonds
Abstract
The total valence of the bonds between acceptors and the H atoms bonded to a water molecule (s d) is taken equal to the bond valence (st) received by the donor 0 atom from coordination bonds. For an OH- group, s d = sr-l. Plots of the bond valence s for H...O bonds as functions of O...O, H...O and O-H distances are fitted with the function s = (R/Ro)-b+ k. The most reliable fitting is obtained for s vs O...O; a minimum value of O...O ~_2.55 A for the hydrogen bonds donated by a water molecule is predicted. Similar curves from the literature are compared and discussed.
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Cited by
The Crystal Structure of Tobermorite 14 Å (Plombierite), a C–S–H Phase
Bonaccorsi, E., Merlino, S., & Kampf, A. R. (2005) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2005.00116.x · Cited by 411
Chukanovite, Fe2(CO3)(OH)2, a new mineral from the weathered iron meteorite Dronino
Pekov, I. V., Perchiazzi, N., Merlino, S., Kalachev, V. N., Merlini, M., & Zadov, A. E. (2007) · European Journal of Mineralogy · doi:10.1127/0935-1221/2007/0019-1767 · Cited by 98
Metadata
- Authors
- Ferraris, G., & Ivaldi, G.
- Venue
- Acta Crystallographica Section B Structural Science
- Published
- 1988-08-01
- Volume
- 44
- Issue
- 4
- Pages
- 341-344
- ISSN
- 0108-7681 (ISSN-L)
- OpenAlex
- W1973167705
- Cited by
- 236
- References
- 0
- FWCI
- 0.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Bond valence vs bond length in O...O hydrogen bonds. https://app.cochat.ai/papers/10.1107/s0108768188001648
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- Ferraris, G., & Ivaldi, G. (1988). Bond valence vs bond length in O...O hydrogen bonds. Acta Crystallographica Section B Structural Science. https://doi.org/10.1107/s0108768188001648
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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