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Octahedral Tilting in Perovskites. I. Geometrical Considerations
Abstract
The 23 Glazer tilt systems describing octahedral tilting in perovskites have been investigated. It is shown that in tilt systems a + a + a −, a + b + b −, a + a + c −, a + b + c −, a 0 b + b − and a 0 b + c − it is not possible to link together a three-dimensional network of perfectly rigid octahedra. In these tilt systems small distortions of the octahedra must occur. The magnitude of the distortions in the a + a + a − and a 0 b + b − tilt systems are estimated. A table of predicted space groups for ordered perovskites, A 2 MM′O 6, for all 23 tilt systems is also given.
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Cited by
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors
Stoumpos, C. C., & Kanatzidis, M. G. (2015) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00229 · Cited by 820
Structural studies of charge disproportionation and magnetic order inCaFeO3
Woodward, P. M., Cox, D. E., Moshopoulou, E., Sleight, A. W., & Morimoto, S. (2000) · Physical Review B · doi:10.1103/physrevb.62.844 · Cited by 308
Self-citationTalapatra, A., Uberuaga, B. P., Stanek, C. R., & Pilania, G. (2021) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c03402 · Cited by 149
Metadata
- Authors
- Woodward, P. M.
- Venue
- Acta Crystallographica Section B Structural Science
- Published
- 1997-02-01
- Volume
- 53
- Issue
- 1
- Pages
- 32-43
- ISSN
- 0108-7681 (ISSN-L)
- OpenAlex
- W2089872971
- Cited by
- 1,126
- References
- 0
- FWCI
- 11.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- Woodward, P. M. (1997). Octahedral Tilting in Perovskites. I. Geometrical Considerations. Acta Crystallographica Section B Structural Science. https://doi.org/10.1107/s0108768196010713
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