The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
The characterisation by liquid chromatography of lake pigments prepared from European buckthorn (Rhamnus cathartica L.)
Open accessAbstract
Purpose: The purpose of this paper is to prepare, analyse and measure the colour values of the lake pigments obtained from the reaction of Al3+, Fe2+ and Sn2+ metal salts with the natural dyes present in European buckthorn (Rhamnus cathartica L.). Design/methodology/approach: A reversed‐phase high performance liquid chromatography (HPLC) with diode‐array detection method was utilised for the identification of buckthorn lake pigments. The extraction of dyes from the lake pigments was carried out with 37% hydrochloric acid/methanol/water (2:1:1; v/v/v) solution. Findings: According to the results of the HPLC analysis of the lake pigments, it was determined that rhamnetin, kaempferol, and emodin were present in the acid hydrolysed plant extract and in the lake pigment that was precipitated by Sn(II), quercetin‐3‐arabinosid, rhamnetin, and emodin were present in the non‐hydrolysed plant extract, and kaempferol, rhamnetin, isorhamnetin, and emodin were found in the lake pigment that was precipitated by Al(III). Rhamnetin and emodin were present in the lake pigment that was precipitated by Fe(II). Research limitations/implications: In the present context for the preparation of buckthorn lake pigments, a simple and practical method is presented. In addition, the analysis of the lake pigments was performed by reversed phase HPLC (RP‐HPLC) with diode array detector (DAD). Practical implications: The paper describes the preparation of lake pigments and their qualitative analysis. This method can be used to determine the origins of the dyestuffs used in historical art pieces. Originality/value: The paper describes the development of methods for the analysis and the preparation of European buckthorn lake pigments.
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“Although the precise stoichiometry and coordination geometry were not determined in this work, the formation of aluminum-phenolic complexes is consistent with mechanisms previously reported for natural lake pigments and metal-mordanted dyes [8,13,39,41,42].”
From Biocompound and Lake Pigment Extraction from Invasive Alien Plant Biomass for Sustainable Ink Applications (2026) · cites this paper as [42]
Citations
Cites
WOUTERS, J. T. M. (1985) · Studies in Conservation · doi:10.1179/sic.1985.30.3.119 · Cited by 246
The coccid insect dyes: hplc and computerized diode-array analysis of dyed yarns
WOUTERS, J. T. M., & Verhecken, A. (1989) · Studies in Conservation · doi:10.1179/sic.1989.34.4.189 · Cited by 171
Characterisation of historical organic dyestuffs by liquid chromatography–mass spectrometry
Rosenberg, E. (2008) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-008-1977-0 · Cited by 150
Vibrational and electronic properties of painting lakes
Clementi, C., Doherty, B., Gentili, P. L., Miliani, C., Romani, A., Brunetti, B. G., & Sgamellotti, A. (2008) · Applied Physics A · doi:10.1007/s00339-008-4474-6 · Cited by 145
Wouters, J., & Rosario-Chirinos, N. (1992) · Journal of the American Institute for Conservation · doi:10.1179/019713692806066637 · Cited by 130
Halpine, S. M. (1996) · Studies in Conservation · doi:10.1179/sic.1996.41.2.76 · Cited by 108
Melo, M. J., & Claro, A. (2010) · Accounts of Chemical Research · doi:10.1021/ar9001894 · Cited by 87
Sanyova, J., & Reisse, J. (2006) · Journal of Cultural Heritage · doi:10.1016/j.culher.2006.06.003 · Cited by 81
Karapanagiotis, I., Lakka, A., Valianou, L., & Chryssoulakis, Y. (2007) · Microchimica Acta · doi:10.1007/s00604-007-0774-4 · Cited by 77
Primary flavonoids in marigold dye: extraction, structure and involvement in the dyeing process
Guinot, P., Gargadennec, A., Valette, G., Fruchier, A., & Andary, C. (2007) · Phytochemical Analysis · doi:10.1002/pca.1014 · Cited by 74
Research works printed but not linked: 2
- Deveoglu, O., Torgan, E., Taskopru, T. and Karadag, R. (2010c), “SEM‐EDX/HPLC analysis and production of natural pigments from Quercus ithaburensis with Al3+, Fe2+ and Sn2+ metals”, Proceeding 6th Conference on Medicinal and Aromatic Plants of Southeast European Countries, Damla Copy Center Matbaa, Antalya, Turkey, pp. 908‐18.
- Karadag, R. and Dolen, E. (2008), “Identification of natural dyes in historical textiles by liquid chromatography”, Proceeding 2nd Residential Summer School, Palermo, Italy, pp. 131‐9.
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Campanella, B., Degano, I., Grifoni, E., Legnaioli, S., Lorenzetti, G., Pagnotta, S., Poggialini, F., & Palleschi, V. (2018) · Microchemical Journal · doi:10.1016/j.microc.2018.02.034 · Cited by 39
Sustainable and Mass Production of Cotton Dyeing with Natural Dye (Weld) in the Textile Industry
Karadağ, R. (2021) · Journal of Natural Fibers · doi:10.1080/15440478.2021.2002781 · Cited by 27
Providing UV Protection Features for Woolen Fabric Using Buckthorn Dye
Benli, H., & Bahtiyari, M. İ. (2022) · Journal of Natural Fibers · doi:10.1080/15440478.2022.2143978 · Cited by 13
Characterisation of illicit ecstasy and diazepam tablets by colorant identification
Sharrenbroch, L., Tough, A., & Matthews, K. H. (2018) · Analytical Methods · doi:10.1039/c7ay02921g · Cited by 6
Mas-Normand, L., Dangles, O., Mathe, C., & Culioli, G. (2025) · Microchemical Journal · doi:10.1016/j.microc.2025.115621 · Cited by 3
Metadata
- Authors
- Deveoglu, O., Torgan, E., & Karadag, R.
- Affiliations
- Turkish Cultural Foundation (US)
- ORCID
- Torgan, Emine
- Venue
- Pigment & Resin Technology
- Publisher
- Emerald
- Published
- 2012-11-02
- Volume
- 41
- Issue
- 6
- Pages
- 331-338
- ISSN
- 0369-9420 (ISSN-L)
- OpenAlex
- W2008757457
- Cited by
- 9
- References
- 22
- Citations by year
- 2026: 1 · 2025: 1 · 2023: 1 · 2022: 1 · 2021: 2 · 2018: 2 · 2015: 1
- FWCI
- 0.49
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Pigment & Resin Technology (publishedVersion)
- Yildiz Technical University - AVESIS (submittedVersion)
- Dspace Repository (Marmara Üniversitesi) (submittedVersion)
- Dspace Repository (Marmara Üniversitesi) (submittedVersion, other-oa)
- Topics
- Life Sciences › Agricultural and Biological Sciences › Food Science › Botanical Research and Applications
- Physical Sciences › Chemistry › Analytical Chemistry › Dye analysis and toxicity
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Phytochemistry and biological activity of medicinal plants
- Keywords
- lake pigments, European buckthorn, Rhamnus cathartica, natural dyes, rhamnetin, emodin, kaempferol, isorhamnetin, acid hydrolysis, dye extraction, pigment identification
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