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Cited by 248

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Compositionally controlled FePt nanoparticle materials

Shouheng Sun, Fullerton, E.E., Weller, D., Murray, C.B.·2001·IEEE Transactions on Magnetics

Abstract

High temperature solution phase decomposition of Fe(CO)/sub 5/ and reduction of Pt(acac)/sub 2/ in the presence of stabilizers, oleic acid and oleyl amine, are employed to produce 4 nm diameter FePt nanoparticles. The Fe and Pt composition of the nanoparticle materials can be tuned by adjusting the molar ratio of Fe(CO)/sub 5/ to Pt(acac)/sub 2/, and the compositions ranging from Fe/sub 30/Pt/sub 70/ to Fe/sub 80/Pt/sub 20/ are obtained. The nanoparticle materials are easily dispersed into alkane solvent, facilitating their self-organization into nanoparticle superlattices. As synthesized FePt nanoparticles possess a disordered fcc structure and show superparamagnetic behavior. Thermal annealing induces a change of internal particle structure and thus of the magnetic properties of the particles. Composition dependent structure analysis shows that an annealed FePt nanoparticle assembly with a composition around Fe/sub 55/Pt/sub 45/ will lead to the highly ordered fct phase. This Fe/sub 55/Pt/sub 45/ nanoparticle assembly yields high coercivity, and will be a candidate for future ultra-high density magnetic recording media applications.

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Metadata

Authors
Sun, S., Fullerton, E. E., Weller, D., & Murray, C. B.
Venue
IEEE Transactions on Magnetics
Published
2001-07
Volume
37
Issue
4
Pages
1239-1243
ISSN
0018-9464 (ISSN-L)
OpenAlex
W2144291054
Cited by
248
References
1
FWCI
12.27
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Compositionally controlled FePt nanoparticle materials. https://app.cochat.ai/papers/10.1109/20.950807
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Sun, S., Fullerton, E. E., Weller, D., & Murray, C. B. (2001). Compositionally controlled FePt nanoparticle materials. IEEE Transactions on Magnetics. https://doi.org/10.1109/20.950807

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