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A Molecular Mechanism for Stress Corrosion in Vitreous Silica
Abstract
The mechanical strength of most glasses and ceramics decreases with time under static loading in an ambient environment. This strength loss is associated with slow growth of preexisting surface flaws due to stress corrosion by water from the surrounding environment. We studied stress corrosion in vitreous silica exposed to water and several nonaqueous environments; environments which enhance stress‐corrosion crack growth in silica contain active groups with electron donor sites on one end and proton donor sites at the other. These results suggest a detailed chemical model for the interaction of the environment with mechanically strained bonds in the solid at the tip of a crack. The proposed model for stress‐corrosion crack growth also has implications for the long‐term strength behavior of a wide variety of brittle materials.
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Cited by
Time-dependent cracking and brittle creep in crustal rocks: A review
Brantut, N., Heap, M. J., Meredith, P. G., & Baud, P. (2013) · Journal of Structural Geology · doi:10.1016/j.jsg.2013.03.007 · Cited by 706
Haldimann, M., Luible, A., & Overend, M. (2008) · doi:10.2749/sed010 · Cited by 300
Mechanical Properties and Brittle Behavior of Silica Aerogels
Woignier, T., Primera, J., Alaoui, A., Etienne, P., Despestis, F., & Calas-Etienne, S. (2015) · Gels · doi:10.3390/gels1020256 · Cited by 117
Metadata
- Authors
- MICHALSKE, T. A., & FREIMAN, S. W.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1983-04
- Volume
- 66
- Issue
- 4
- Pages
- 284-288
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2131300332
- Cited by
- 535
- References
- 0
- FWCI
- 14.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A Molecular Mechanism for Stress Corrosion in Vitreous Silica. https://app.cochat.ai/papers/10.1111/j.1151-2916.1983.tb15715.x
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- MICHALSKE, T. A., & FREIMAN, S. W. (1983). A Molecular Mechanism for Stress Corrosion in Vitreous Silica. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1983.tb15715.x
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
