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dc Electrical Degradation of Perovskite‐Type Titanates: II, Single Crystals
Abstract
The resistance degradation of Al‐doped, Ni‐doped, and Fedoped SrTiO 3 single crystals is studied as a function of the temperature and the applied dc voltage. The individual influence of the acceptor dopants is discussed. Data of the mobility of oxygen vacancies are obtained from the determination of the time evolution of the electric field distribution between the electrodes, from electrocoloration studies, and from an examination of the thermal annealing after degradation. In a numerical calculation based on the defect chemistry and transport properties of titanates, the electrocoloration process is simulated and a qualitative explanation of the degradation process is presented.
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Cited by
Redox‐Based Resistive Switching Memories – Nanoionic Mechanisms, Prospects, and Challenges
Waser, R., Dittmann, R., Staikov, G., & Szot, K. (2009) · Advanced Materials · doi:10.1002/adma.200900375 · Cited by 5,080
Self-citationQuantitative measurement of space-charge effects in lead zirconate-titanate memories
Scott, J. F., Araujo, C. A., Melnick, B. M., McMillan, L. D., & Zuleeg, R. (1991) · Journal of Applied Physics · doi:10.1063/1.350286 · Cited by 517
Oxygen Vacancy Motion in Perovskite Oxides
Warren, W. L., Vanheusden, K., Dimos, D., Pike, G. E., & Tuttle, B. A. (1996) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1996.tb08162.x · Cited by 331
Metadata
- Authors
- Waser, R., Baiatu, T., & Härdtl, K.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1990-06
- Volume
- 73
- Issue
- 6
- Pages
- 1654-1662
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2107133220
- Cited by
- 342
- References
- 0
- FWCI
- 6.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Waser, R., Baiatu, T., & Härdtl, K. (1990). dc Electrical Degradation of Perovskite‐Type Titanates: II, Single Crystals. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1990.tb09810.x
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