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Phenomenological Theory of High Permittivity in Fine‐Grained Barium Titanate
Abstract
The anomalously high permittivity in fine‐grained ceramic barium titanate is explained by the absence of 90° twinning within the grains, giving rise to internal stresses as the ceramic cools below the Curie temperature. Using the Devonshire phenomenological thermodynamic method and a simplified model, the stresses involved are calculated. At these stresses levels, the reduced strain calculated on this model agrees well with X‐ray data for the fine‐grained material. The limitations and possible developments of the proposed model are discussed.
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Cites
Bruggeman, D. A. G. (1935) · Annalen der Physik · doi:10.1002/andp.19354160705 · Cited by 8,645
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Shaw, T. M., Trolier-McKinstry, S., & McIntyre, P. C. (2000) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.30.1.263 · Cited by 531
Hao, J., Bai, W., Li, W., & Zhai, J. (2012) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2012.05146.x · Cited by 440
Cold Sintering Process: A Novel Technique for Low‐Temperature Ceramic Processing of Ferroelectrics
Guo, H., Baker, A., Guo, J., & Randall, C. A. (2016) · Journal of the American Ceramic Society · doi:10.1111/jace.14554 · Cited by 426
Perspectives and challenges in multilayer ceramic capacitors for next generation electronics
Hong, K., Lee, T. H., Suh, J. M., Yoon, S.-H., & Jang, H. W. (2019) · Journal of Materials Chemistry C · doi:10.1039/c9tc02921d · Cited by 382
Unfolding grain size effects in barium titanate ferroelectric ceramics
Tan, Y., Zhang, J., Wu, Y., Wang, C., Koval, V., Shi, B., Ye, H., McKinnon, R., Viola, G., & Yan, H. (2015) · Scientific Reports · doi:10.1038/srep09953 · Cited by 379
Metadata
- Authors
- BUESSEM, W. R., CROSS, L. E., & GOSWAMI, A. K.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1992-11
- Volume
- 75
- Issue
- 11
- Pages
- 2923-2926
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W4238165172
- Cited by
- 446
- References
- 1
- FWCI
- 10.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- BUESSEM, W. R., CROSS, L. E., & GOSWAMI, A. K. (1992). Phenomenological Theory of High Permittivity in Fine‐Grained Barium Titanate. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1992.tb04362.x
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
