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Electrophoretic Deposition (EPD): Mechanisms, Kinetics, and Application to Ceramics
Abstract
The mechanisms of electrophoretic deposition (EPD) are discussed and their shortcomings identified. The kinetics of the processes involved are analyzed for constant‐current and constant‐voltage conditions. A method of determining the Hamaker constant of suspended particles is developed by modeling the relationship between the particle inter‐action energy and the suspension stability. A three‐probe dc technique is used to map the voltage profile around the depositing electrode, and the results are used to explain discrepancies between the calculated and experimentally observed voltage drops during deposition. A mechanism of deposition is proposed based on DLVO theory and particle double‐layer distortion/thinning on application of a dc field to the suspension. Kinetic equations are developed for constant‐current and constant‐voltage EPD using mass balance conditions; these are verified by experiments. After the phenomenon is introduced and discussed, a critique of the application of EPD to the synthesis of ceramic shapes and coatings is given.
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Citations
Cited by
Colloidal Processing of Ceramics
Lewis, J. A. (2000) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.2000.tb01560.x · Cited by 1,371
ELECTROPHORETIC DEPOSITION OF MATERIALS
Van der Biest, O. O., & Vandeperre, L. J. (1999) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.29.1.327 · Cited by 782
Electrophoretic deposition of biomaterials
Boccaccini, A. R., Keim, S., Ma, R., Li, Y., & Zhitomirsky, I. (2010) · Journal of The Royal Society Interface · doi:10.1098/rsif.2010.0156.focus · Cited by 760
Electrophoretic deposition: From traditional ceramics to nanotechnology
Corni, I., Ryan, M. P., & Boccaccini, A. R. (2008) · Journal of the European Ceramic Society · doi:10.1016/j.jeurceramsoc.2007.12.011 · Cited by 731
Electrophoretic deposition of carbon nanotubes
Boccaccini, A. R., Cho, J., Roether, J. A., Thomas, B. J. C., Jane Minay, E., & Shaffer, M. S. P. (2006) · Carbon · doi:10.1016/j.carbon.2006.06.021 · Cited by 678
Metadata
- Authors
- Sarkar, P., & Nicholson, P. S.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1996-08
- Volume
- 79
- Issue
- 8
- Pages
- 1987-2002
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2108851629
- Cited by
- 1,284
- References
- 0
- FWCI
- 14.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electrophoretic Deposition (EPD): Mechanisms, Kinetics, and Application to Ceramics. https://app.cochat.ai/papers/10.1111/j.1151-2916.1996.tb08929.x
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- Sarkar, P., & Nicholson, P. S. (1996). Electrophoretic Deposition (EPD): Mechanisms, Kinetics, and Application to Ceramics. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1996.tb08929.x
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
