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Intrinsic and Extrinsic Size Effects in Fine‐Grained Morphotropic‐Phase‐Boundary Lead Zirconate Titanate Ceramics
Abstract
The processing, electromechanical properties, and microstructure of lead zirconate titanate (PZT) ceramics over the grain‐size range of 0.1‐10 μm were studied. Using measurements over a large temperature range (15‐600 K), the relative role of extrinsic contribution (i.e., domain‐wall motion) was deduced to be influenced strongly by the grain size, particularly for donor‐doped PZT. Analytical transmission electron microscopy studies were conducted to investigate the trend in domain configurations with the reduction of grain size. The correlations between domain density, domain variants, domain configurations (before and after poling), spontaneous deformation, and the elastodielectric properties were qualitatively discussed, leading to new insights into the intrinsic and extrinsic effects and relevant size effects in ferroelectric polycrystalline materials.
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Cited by
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Acosta, M., Novak, N., Rojas, V., Patel, S., Vaish, R., Koruza, J., Rossetti, G. A., & Rödel, J. (2017) · Applied Physics Reviews · doi:10.1063/1.4990046 · Cited by 1,451
An organic-inorganic perovskite ferroelectric with large piezoelectric response
You, Y.-M., Liao, W.-Q., Zhao, D., Ye, H.-Y., Zhang, Y., Zhou, Q., Niu, X., Wang, J., Li, P.-F., Fu, D.-W., et al. (2017) · Science · doi:10.1126/science.aai8535 · Cited by 1,081
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Friend, J., & Yeo, L. Y. (2011) · Reviews of Modern Physics · doi:10.1103/revmodphys.83.647 · Cited by 964
Unfolding grain size effects in barium titanate ferroelectric ceramics
Tan, Y., Zhang, J., Wu, Y., Wang, C., Koval, V., Shi, B., Ye, H., McKinnon, R., Viola, G., & Yan, H. (2015) · Scientific Reports · doi:10.1038/srep09953 · Cited by 379
Pramanick, A., Damjanovic, D., Nino, J. C., & Jones, J. L. (2009) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2009.03218.x · Cited by 80
Metadata
- Authors
- Randall, C. A., Kim, N., Kucera, J., Cao, W., & Shrout, T. R.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 1998-03
- Volume
- 81
- Issue
- 3
- Pages
- 677-688
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2161129668
- Cited by
- 1,063
- References
- 0
- FWCI
- 13.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Randall, C. A., Kim, N., Kucera, J., Cao, W., & Shrout, T. R. (1998). Intrinsic and Extrinsic Size Effects in Fine‐Grained Morphotropic‐Phase‐Boundary Lead Zirconate Titanate Ceramics. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.1998.tb02389.x
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