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Preparation of Li 2 S–P 2 S 5 Amorphous Solid Electrolytes by Mechanical Milling
Abstract
Amorphous solid electrolytes in the Li 2 S–P 2 S 5 system were prepared successfully from a mixture of crystalline Li 2 S and P 2 S 5 , using a mechanical milling technique. The amorphous‐forming region was extended to higher Li 2 S compositions by mechanical milling, compared with melt quenching. The pelletized samples of the 75Li 2 S·25P 2 S 5 (on a mole‐percent basis) amorphous powders obtained by mechanical milling for 20 h exhibited high conductivity (2 × 10 −4 S/cm at room temperature) and an activation energy for conduction of 34 kJ/mol. The lithium‐ion transport number of the amorphous powders was almost unity.
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Cited by
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Fan, X., Ji, X., Chen, L., Chen, J., Deng, T., Han, F., Yue, J., Piao, N., Wang, R., Zhou, X., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0474-3 · Cited by 938
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Metadata
- Authors
- Hayashi, A., Hama, S., Morimoto, H., Tatsumisago, M., & Minami, T.
- Venue
- Journal of the American Ceramic Society
- Publisher
- Wiley
- Published
- 2001-02
- Volume
- 84
- Issue
- 2
- Pages
- 477-79
- ISSN
- 0002-7820 (ISSN-L)
- 1551-2916
- OpenAlex
- W2120632249
- Cited by
- 478
- References
- 0
- FWCI
- 9.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Preparation of Li 2 S–P 2 S 5 Amorphous Solid Electrolytes by Mechanical Milling. https://app.cochat.ai/papers/10.1111/j.1151-2916.2001.tb00685.x
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- Hayashi, A., Hama, S., Morimoto, H., Tatsumisago, M., & Minami, T. (2001). Preparation of Li 2 S–P 2 S 5 Amorphous Solid Electrolytes by Mechanical Milling. Journal of the American Ceramic Society. https://doi.org/10.1111/j.1151-2916.2001.tb00685.x
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