The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
A clicking confinement strategy to fabricate transition metal single-atom sites for bifunctional oxygen electrocatalysis
Open accessAbstract
Rechargeable zinc-air batteries call for high-performance bifunctional oxygen electrocatalysts. Transition metal single-atom catalysts constitute a promising candidate considering their maximum atom efficiency and high intrinsic activity. However, the fabrication of atomically dispersed transition metal sites is highly challenging, creating a need for for new design strategies and synthesis methods. Here, a clicking confinement strategy is proposed to efficiently predisperse transitional metal atoms in a precursor directed by click chemistry and ensure successful construction of abundant single-atom sites. Concretely, cobalt-coordinated porphyrin units are covalently clicked on the substrate for the confinement of the cobalt atoms and affording a Co-N-C electrocatalyst. The Co-N-C electrocatalyst exhibits impressive bifunctional oxygen electrocatalytic performances with an activity indicator Δ E of 0.79 V. This work extends the approach to prepare transition metal single-atom sites for efficient bifunctional oxygen electrocatalysis and inspires the methodology on precise synthesis of catalytic materials.
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Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation
Xiong, Y., Dong, J., Huang, Z.-Q., Xin, P., Chen, W., Wang, Y., Li, Z., Jin, Z., Xing, W., Zhuang, Z., et al. (2020) · Nature Nanotechnology · doi:10.1038/s41565-020-0665-x · Cited by 610
Self-citationWang, Q., Shang, L., Shi, R., Zhang, X., Zhao, Y., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700467 · Cited by 508
Cheng, W., Zhang, H., Luan, D., & Lou, X. W. (. (2021) · Science Advances · doi:10.1126/sciadv.abg2580 · Cited by 319
Cited by
Zn-based batteries for sustainable energy storage: strategies and mechanisms
Tang, L., Peng, H., Kang, J., Chen, H., Zhang, M., Liu, Y., Kim, D. H., Liu, Y., & Lin, Z. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00295k · Cited by 548
High-entropy single-atom activated carbon catalysts for sustainable oxygen electrocatalysis
Lei, X., Tang, Q., Zheng, Y., Kidkhunthod, P., Zhou, X., Ji, B., & Tang, Y. (2023) · Nature Sustainability · doi:10.1038/s41893-023-01101-z · Cited by 419
Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS)
Song, W., Xiao, C., Ding, J., Huang, Z., Yang, X., Zhang, T., Mitlin, D., & Hu, W. (2024) · Advanced Materials · doi:10.1002/adma.202301477 · Cited by 373
Shen, M., Hu, W., Duan, C., Li, J., Ding, S., Zhang, L., Zhu, J., & Ni, Y. (2023) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2022.09.035 · Cited by 67
Ferro-catalysis Bioelectronics: Progress and Prospects
Tang, X., Liu, Y., Li, L., Song, Y., Dai, Y., Yang, Y., Yuan, G., & Wang, Y. (2024) · Nano Energy · doi:10.1016/j.nanoen.2023.109059 · Cited by 8
Metadata
- Authors
- Zhao, C.-X., Liu, J.-N., Wang, J., Wang, C., Guo, X., Li, X.-Y., Chen, X., Song, L., Li, B.-Q., & Zhang, Q.
- Venue
- Science Advances
- Published
- 2022-03-18
- Volume
- 8
- Issue
- 11
- Pages
- eabn5091-eabn5091
- ISSN
- 2375-2548 (ISSN-L)
- OpenAlex
- W4220953740
- Cited by
- 262
- References
- 3
- FWCI
- 10.39
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhao, C.-X., Liu, J.-N., Wang, J., Wang, C., Guo, X., Li, X.-Y., Chen, X., Song, L., Li, B.-Q., & Zhang, Q. (2022). A clicking confinement strategy to fabricate transition metal single-atom sites for bifunctional oxygen electrocatalysis. Science Advances. https://doi.org/10.1126/sciadv.abn5091
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