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Cited by 262

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A clicking confinement strategy to fabricate transition metal single-atom sites for bifunctional oxygen electrocatalysis

Open access
Zhao, Chang-Xin, Liu, Jia-Ning, Wang, Juan, Wang, Changda, Guo, Xin, Li, Xi-Yao, Chen, Xiao, Song, Li, Li, Bo-Quan, Zhang, Qiang·2022·Science Advances

Abstract

Rechargeable zinc-air batteries call for high-performance bifunctional oxygen electrocatalysts. Transition metal single-atom catalysts constitute a promising candidate considering their maximum atom efficiency and high intrinsic activity. However, the fabrication of atomically dispersed transition metal sites is highly challenging, creating a need for for new design strategies and synthesis methods. Here, a clicking confinement strategy is proposed to efficiently predisperse transitional metal atoms in a precursor directed by click chemistry and ensure successful construction of abundant single-atom sites. Concretely, cobalt-coordinated porphyrin units are covalently clicked on the substrate for the confinement of the cobalt atoms and affording a Co-N-C electrocatalyst. The Co-N-C electrocatalyst exhibits impressive bifunctional oxygen electrocatalytic performances with an activity indicator Δ E of 0.79 V. This work extends the approach to prepare transition metal single-atom sites for efficient bifunctional oxygen electrocatalysis and inspires the methodology on precise synthesis of catalytic materials.

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Metadata

Authors
Zhao, C.-X., Liu, J.-N., Wang, J., Wang, C., Guo, X., Li, X.-Y., Chen, X., Song, L., Li, B.-Q., & Zhang, Q.
Venue
Science Advances
Published
2022-03-18
Volume
8
Issue
11
Pages
eabn5091-eabn5091
ISSN
2375-2548 (ISSN-L)
OpenAlex
W4220953740
Cited by
262
References
3
FWCI
10.39
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: A clicking confinement strategy to fabricate transition metal single-atom sites for bifunctional oxygen electrocatalysis. https://app.cochat.ai/papers/10.1126/sciadv.abn5091
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Zhao, C.-X., Liu, J.-N., Wang, J., Wang, C., Guo, X., Li, X.-Y., Chen, X., Song, L., Li, B.-Q., & Zhang, Q. (2022). A clicking confinement strategy to fabricate transition metal single-atom sites for bifunctional oxygen electrocatalysis. Science Advances. https://doi.org/10.1126/sciadv.abn5091

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