Cited by 696Atmospheric chemistry and aerosolsAtmospheric Ozone and ClimateAtmospheric and Environmental Gas Dynamics

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Evidence for Substantial Variations of Atmospheric Hydroxyl Radicals in the Past Two Decades

Prinn, R. G., Huang, J., Weiss, R. F., Cunnold, D. M., Fraser, P. J., Simmonds, P. G., McCulloch, A., Harth, C., Salameh, P., O'Doherty, S., Wang, R. H. J., Porter, L., Miller, B. R.·2001·Science

DOI 10.1126/science.1058673

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Abstract

The hydroxyl radical (OH) is the dominant oxidizing chemical in the atmosphere. It destroys most air pollutants and many gases involved in ozone depletion and the greenhouse effect. Global measurements of 1,1,1-trichloroethane (CH 3 CCl 3 , methyl chloroform) provide an accurate method for determining the global and hemispheric behavior of OH. Measurements show that CH 3 CCl 3 levels rose steadily from 1978 to reach a maximum in 1992 and then decreased rapidly to levels in 2000 that were lower than the levels when measurements began in 1978. Analysis of these observations shows that global OH levels were growing between 1978 and 1988, but the growth rate was decreasing at a rate of 0.23 ± 0.18% year −2 , so that OH levels began declining after 1988. Overall, the global average OH trend between 1978 and 2000 was −0.64 ± 0.60% year −1 . These variations imply important and unexpected gaps in current understanding of the capability of the atmosphere to cleanse itself.

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Supplementary material is available at Science Online at www.sciencemag.org/cgi/content/full/1058673/DC1.
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Authors: Prinn, R. G., Huang, J., Weiss, R. F., Cunnold, D. M., Fraser, P. J., Simmonds, P. G., McCulloch, A., Harth, C., Salameh, P., O'Doherty, S., Wang, R. H. J., Porter, L., & Miller, B. R.
Affiliations: Massachusetts Institute of Technology (US)
Scripps Institution of Oceanography (US)
Georgia Institute of Technology (US)
Commonwealth Scientific and Industrial Research Organisation (AU)
University of Bristol (GB)
School of Chemistry, University of Bristol, Bristol 8S8 1TH, UK.
Bureau of Meteorology (AU)
ORCID: Prinn, R. G.
Weiss, R. F.
Fraser, P. J.
Simmonds, P. G.
McCulloch, A.
Harth, C.
Venue: Science
Publisher: American Association for the Advancement of Science (AAAS)
Published: 2001-06-08
Volume: 292
Issue: 5523
Pages: 1882-1888
ISSN: 0036-8075 (ISSN-L)
1095-9203
DOI: 10.1126/science.1058673
OpenAlex: W2115751232
Cited by: 695
References: 29
Citations by year: 2026: 28 · 2025: 33 · 2024: 18 · 2023: 25 · 2022: 23 · 2021: 58 · 2020: 19 · 2019: 28 · 2018: 28 · 2017: 21 · 2016: 19 · 2015: 22 · 2014: 26 · 2013: 29 · 2012: 24
FWCI: 27.42
Type: journal article
Language: en
Open access: closed
Locations: Science (publishedVersion)
PubMed (publishedVersion)
Bristol Research (University of Bristol) (submittedVersion)
Topics: Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric and Environmental Gas Dynamics
Keywords: hydroxyl radicals, 1,1,1-trichloroethane, atmospheric oxidation capacity, ozone depletion, greenhouse effect, air pollutant removal, global atmospheric chemistry

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Evidence for Substantial Variations of Atmospheric Hydroxyl Radicals in the Past Two Decades

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