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Water at Hydrophobic Surfaces: Weak Hydrogen Bonding and Strong Orientation Effects
Abstract
Vibrational studies that selectively probe molecular structure at CCl 4 /H 2 O and hydrocarbon/H 2 O interfaces show that the hydrogen bonding between adjacent water molecules at these interfaces is weak, in contrast to generally accepted models of water next to fluid hydrophobic surfaces that suggest strong hydrogen bonding. However, interactions between these water molecules and the organic phase result in substantial orientation of these weakly hydrogen-bonded water molecules in the interfacial region. The results have important implications for understanding water adjacent to hydrophobic surfaces and the penetration of water into hydrophobic phases.
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Citations
Cited by
Cammarata, L., Kazarian, S. G., Salter, P. A., & Welton, T. (2001) · Physical Chemistry Chemical Physics · doi:10.1039/b106900d · Cited by 1,441
Water in Nanoconfinement between Hydrophilic Self-Assembled Monolayers
Lane, J. M. D., Chandross, M., Stevens, M. J., & Grest, G. S. (2008) · Langmuir · doi:10.1021/la704005v · Cited by 52
Bunkin, N. F., Ninham, B. W., Babenko, V. A., Suyazov, N. V., & Sychev, A. A. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp101657f · Cited by 36
Hydrogen-Bond-Assisted Excited-State Deactivation at Liquid/Water Interfaces
Fita, P., Fedoseeva, M., & Vauthey, E. (2011) · Langmuir · doi:10.1021/la104801h · Cited by 28
Metadata
- Authors
- Scatena, L. F., Brown, M. G., & Richmond, G. L.
- Venue
- Science
- Published
- 2001-05-04
- Volume
- 292
- Issue
- 5518
- Pages
- 908-912
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2069777400
- Cited by
- 1,137
- References
- 0
- FWCI
- 23.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Scatena, L. F., Brown, M. G., & Richmond, G. L. (2001). Water at Hydrophobic Surfaces: Weak Hydrogen Bonding and Strong Orientation Effects. Science. https://doi.org/10.1126/science.1059514
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