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Cited by 1,246

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Conductance Switching in Single Molecules Through Conformational Changes

Donhauser, Z. J., Mantooth, B. A., Kelly, K. F., Bumm, L. A., Monnell, J. D., Stapleton, J. J., Price, D. W., Rawlett, A. M., Allara, D. L., Tour, J. M., Weiss, P. S.·2001·Science

Abstract

We tracked over time the conductance switching of single and bundled phenylene ethynylene oligomers isolated in matrices of alkanethiolate monolayers. The persistence times for isolated and bundled molecules in either the ON or OFF switch state range from seconds to tens of hours. When the surrounding matrix is well ordered, the rate at which the inserted molecules switch is low. Conversely, when the surrounding matrix is poorly ordered, the inserted molecules switch more often. We conclude that the switching is a result of conformational changes in the molecules or bundles, rather than electrostatic effects of charge transfer.

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Metadata

Authors
Donhauser, Z. J., Mantooth, B. A., Kelly, K. F., Bumm, L. A., Monnell, J. D., Stapleton, J. J., Price, D. W., Rawlett, A. M., Allara, D. L., Tour, J. M., & Weiss, P. S.
Venue
Science
Published
2001-06-22
Volume
292
Issue
5525
Pages
2303-2307
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2133899617
Cited by
1,246
References
0
FWCI
103.30
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Conductance Switching in Single Molecules Through Conformational Changes. https://app.cochat.ai/papers/10.1126/science.1060294
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Donhauser, Z. J., Mantooth, B. A., Kelly, K. F., Bumm, L. A., Monnell, J. D., Stapleton, J. J., Price, D. W., Rawlett, A. M., Allara, D. L., Tour, J. M., & Weiss, P. S. (2001). Conductance Switching in Single Molecules Through Conformational Changes. Science. https://doi.org/10.1126/science.1060294

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.