The DOI matches its Crossref record.
Application of the Marcus Cross Relation to Hydrogen Atom Transfer Reactions
Abstract
The transfer of a hydrogen atom—a proton and an electron—is a fundamental process in chemistry and biology. A variety of hydrogen atom transfer reactions, involving iron complexes, phenols, hydroxylamines, t BuOOH, toluene, and related radicals, are shown to follow the Marcus cross relation. Thus, the Marcus theory formalism based on ground-state energetics and self-exchange rates, originally developed for electron transfer processes, is also valuable for hydrogen atom transfer. Compounds that undergo slow proton transfer (C–H bonds) or slow electron transfer (cobalt complexes) also undergo slow hydrogen atom transfer. Limitations of this approach are also discussed.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory
Mayer, J. M. (2011) · Accounts of Chemical Research · doi:10.1021/ar100093z · Cited by 910
Self-citationConte, M., Miyamura, H., Kobayashi, S., & Chechik, V. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809883c · Cited by 259
Metadata
- Authors
- Roth, J. P., Yoder, J. C., Won, T.-J., & Mayer, J. M.
- Venue
- Science
- Published
- 2001-12-21
- Volume
- 294
- Issue
- 5551
- Pages
- 2524-2526
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1991692692
- Cited by
- 178
- References
- 0
- FWCI
- 4.55
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Application of the Marcus Cross Relation to Hydrogen Atom Transfer Reactions. https://app.cochat.ai/papers/10.1126/science.1066130
- The paper
- Roth, J. P., Yoder, J. C., Won, T.-J., & Mayer, J. M. (2001). Application of the Marcus Cross Relation to Hydrogen Atom Transfer Reactions. Science. https://doi.org/10.1126/science.1066130
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
