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Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid
Abstract
We report the direct observation of dioxygen molecules physisorbed in the nanochannels of a microporous copper coordination polymer by the MEM (maximum entropy method)/Rietveld method, using in situ high-resolution synchrotron x-ray powder diffraction measurements. The obtained MEM electron density revealed that van der Waals dimers of physisorbed O 2 locate in the middle of nanochannels and form a one-dimensional ladder structure aligned to the host channel structure. The observed O–O stretching Raman band and magnetic susceptibilities are characteristic of the confined O 2 molecules in one-dimensional nanochannels of CPL-1 (coordination polymer 1 with pillared layer structure).
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Citations
Cited by
Functional Porous Coordination Polymers
Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071
Self-citationMetal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Highly controlled acetylene accommodation in a metal–organic microporous material
Matsuda, R., Kitaura, R., Kitagawa, S., Kubota, Y., Belosludov, R. V., Kobayashi, T. C., Sakamoto, H., Chiba, T., Takata, M., Kawazoe, Y., et al. (2005) · Nature · doi:10.1038/nature03852 · Cited by 1,520
Self-citationHasegawa, S., Horike, S., Matsuda, R., Furukawa, S., Mochizuki, K., Kinoshita, Y., & Kitagawa, S. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067374y · Cited by 954
Self-citationVaidhyanathan, R., Iremonger, S. S., Shimizu, G. K. H., Boyd, P. G., Alavi, S., & Woo, T. K. (2010) · Science · doi:10.1126/science.1194237 · Cited by 927
Metadata
- Authors
- Kitaura, R., Kitagawa, S., Kubota, Y., Kobayashi, T. C., Kindo, K., Mita, Y., Matsuo, A., Kobayashi, M., Chang, H.-C., Ozawa, T. C., Suzuki, M., Sakata, M., & Takata, M.
- Venue
- Science
- Published
- 2002-12-20
- Volume
- 298
- Issue
- 5602
- Pages
- 2358-2361
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2106828600
- Cited by
- 627
- References
- 0
- FWCI
- 22.55
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kitaura, R., Kitagawa, S., Kubota, Y., Kobayashi, T. C., Kindo, K., Mita, Y., Matsuo, A., Kobayashi, M., Chang, H.-C., Ozawa, T. C., Suzuki, M., Sakata, M., & Takata, M. (2002). Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid. Science. https://doi.org/10.1126/science.1078481
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