The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Direct Fabrication of Large Micropatterned Single Crystals
Abstract
Micropatterning of single crystals for technological applications is a complex, multistep process. Nature provides alternative fabrication strategies, when crystals with exquisite micro-ornamentation directly develop within preorganized frameworks. We report a bio-inspired approach to growing large micropatterned single crystals. Micropatterned templates organically modified to induce the formation of metastable amorphous calcium carbonate were imprinted with calcite nucleation sites. The template-directed deposition and crystallization of the amorphous phase resulted in the fabrication of millimeter-sized single calcite crystals with sub–10-μm patterns and controlled crystallographic orientation. We suggest that in addition to regulating the shape, micropatterned frameworks act as sites for stress and impurity release during the amorphous-to-crystalline transition. The proposed mechanisms may have direct biological relevance and broad implications in materials synthesis.
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Citations
Cites
Amorphous calcium carbonate transforms into calcite during sea urchin larval spicule growth
Beniash, E., Aizenberg, J., Addadi, L., & Weiner, S. (1997) · Proceedings of the Royal Society of London. Series B: Biological Sciences · doi:10.1098/rspb.1997.0066 · Cited by 729
Self-citationThermodynamics of Calcite Growth: Baseline for Understanding Biomineral Formation
Teng, H. H., Dove, P. M., Orme, C. A., & De Yoreo, J. J. (1998) · Science · doi:10.1126/science.282.5389.724 · Cited by 490
Cited by
(2007) · Project Muse (Johns Hopkins University) · Cited by 7,214
Bioinspired structural materials
Wegst, U. G. K., Bai, H., Saiz, E., Tomsia, A. P., & Ritchie, R. O. (2015) · Nature Materials · doi:10.1038/nmat4089 · Cited by 4,721
Fabrication of novel biomaterials through molecular self-assembly
Zhang, S. (2003) · Nature Biotechnology · doi:10.1038/nbt874 · Cited by 3,347
Taking advantage of disorder: amorphous calcium carbonate and its roles in biomineralization
Addadi, L., Raz, S., & Weiner, S. (2003) · Advanced Materials · doi:10.1002/adma.200300381 · Cited by 1,594
Hierarchically porous materials: synthesis strategies and structure design
Yang, X.-Y., Chen, L.-H., Li, Y., Rooke, J. C., Sanchez, C., & Su, B.-L. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00829a · Cited by 1,439
Metadata
- Authors
- Aizenberg, J., Muller, D. A., Grazul, J. L., & Hamann, D. R.
- Venue
- Science
- Published
- 2003-02-21
- Volume
- 299
- Issue
- 5610
- Pages
- 1205-1208
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2019867710
- Cited by
- 540
- References
- 2
- FWCI
- 23.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- Aizenberg, J., Muller, D. A., Grazul, J. L., & Hamann, D. R. (2003). Direct Fabrication of Large Micropatterned Single Crystals. Science. https://doi.org/10.1126/science.1079204
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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