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A Discrete Self-Assembled Metal Array in Artificial DNA
Abstract
DNA has a structural basis to array functionalized building blocks. Here we report the synthesis of a series of artificial oligonucleotides, d(5′-G H n C-3′) ( n = 1 to 5), with hydroxypyridone nucleobases ( H ) as flat bidentate ligands. Right-handed double helices of the oligonucleotides, n Cu 2+ ·d(5′-G H n C-3′) 2 ( n = 1 to 5), were quantitatively formed through copper ion (Cu 2+ )–mediated alternative base pairing ( H -Cu 2+ - H ), where the Cu 2+ ions incorporated into each complex were aligned along the helix axes inside the duplexes with the Cu 2+ -Cu 2+ distance of 3.7 ± 0.1 angstroms. The Cu 2+ ions were coupled ferromagnetically with one another through unpaired d electrons to form magnetic chains.
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Cited by
Seeman, N. C., & Sleiman, H. F. (2017) · Nature Reviews Materials · doi:10.1038/natrevmats.2017.68 · Cited by 1,875
Metal-Mediated DNA Base Pairing: Alternatives to Hydrogen-Bonded Watson–Crick Base Pairs
Takezawa, Y., & Shionoya, M. (2012) · Accounts of Chemical Research · doi:10.1021/ar200313h · Cited by 361
Self-citationA dissipative pathway for the structural evolution of DNA fibres
Rizzuto, F. J., Platnich, C. M., Luo, X., Shen, Y., Dore, M. D., Lachance-Brais, C., Guarné, A., Cosa, G., & Sleiman, H. F. (2021) · Nature Chemistry · doi:10.1038/s41557-021-00751-w · Cited by 120
Metadata
- Authors
- Tanaka, K., Tengeiji, A., Kato, T., Toyama, N., & Shionoya, M.
- Venue
- Science
- Published
- 2003-02-21
- Volume
- 299
- Issue
- 5610
- Pages
- 1212-1213
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2020246057
- Cited by
- 565
- References
- 0
- FWCI
- 11.15
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tanaka, K., Tengeiji, A., Kato, T., Toyama, N., & Shionoya, M. (2003). A Discrete Self-Assembled Metal Array in Artificial DNA. Science. https://doi.org/10.1126/science.1080587
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