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Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide
Abstract
Epoxides are an important class of industrial chemicals that have been used as chemical intermediates. Catalytic epoxidation of olefins affords an interesting production technology. We found a widely usable green route to the production of epoxides: A silicotungstate compound, [γ-SiW 10 O 34 (H 2 O) 2 ] 4– , is synthesized by protonation of a divacant, lacunary, Keggin-type polyoxometalate of [γ-SiW 10 O 36 ] 8– and exhibits high catalytic performance for the epoxidation of various olefins, including propylene, with a hydrogen peroxide (H 2 O 2 ) oxidant at 305 kelvin. The effectiveness of this catalyst is evidenced by ≥99% selectivity to epoxide, ≥99% efficiency of H 2 O 2 utilization, high stereospecificity, and easy recovery of the catalyst from the homogeneous reaction mixture.
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Cited by
Green oxidation with aqueous hydrogen peroxide
Noyori, R., Aoki, M., & Sato, K. (2003) · Chemical Communications · doi:10.1039/b303160h · Cited by 1,085
The integration of green chemistry into future biorefineries
H. Clark, J., E. I. Deswarte, F., & J. Farmer, T. (2009) · Biofuels, Bioproducts and Biorefining · doi:10.1002/bbb.119 · Cited by 241
Metadata
- Authors
- Kamata, K., Yonehara, K., Sumida, Y., Yamaguchi, K., Hikichi, S., & Mizuno, N.
- Venue
- Science
- Published
- 2003-05-09
- Volume
- 300
- Issue
- 5621
- Pages
- 964-966
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2071050467
- Cited by
- 648
- References
- 0
- FWCI
- 17.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kamata, K., Yonehara, K., Sumida, Y., Yamaguchi, K., Hikichi, S., & Mizuno, N. (2003). Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide. Science. https://doi.org/10.1126/science.1083176
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