The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Privileged Chiral Catalysts
Abstract
One of the most active current areas of chemical research is centered on how to synthesize handed (chiral) compounds in a selective manner, rather than as mixtures of mirror-image forms (enantiomers) with different three-dimensional structures (stereochemistries). Nature points the way in this endeavor: different enantiomers of a given biomolecule can exhibit dramatically different biological activities, and enzymes have therefore evolved to catalyze reactions with exquisite selectivity for the formation of one enantiomeric form over the other. Drawing inspiration from these natural catalysts, chemists have developed a variety of synthetic small-molecule catalysts that can achieve levels of selectivity approaching, and in some cases matching, those observed in enzymatic reactions.
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Citations
Cites
Asymmetric Catalysis of Epoxide Ring-Opening Reactions
Jacobsen, E. N. (2000) · Accounts of Chemical Research · doi:10.1021/ar960061v · Cited by 1,261
Self-citation
Cited by
Xia, T., Kovochich, M., Brant, J., Hotze, M., Sempf, J., Oberley, T., Sioutas, C., Yeh, J. I., Wiesner, M. R., & Nel, A. E. (2006) · Nano Letters · doi:10.1021/nl061025k · Cited by 1,918
Towards the online computer-aided design of catalytic pockets
Falivene, L., Cao, Z., Petta, A., Serra, L., Poater, A., Oliva, R., Scarano, V., & Cavallo, L. (2019) · Nature Chemistry · doi:10.1038/s41557-019-0319-5 · Cited by 1,290
Phosphoramidites: Privileged Ligands in Asymmetric Catalysis
Teichert, J. F., & Feringa, B. L. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200904948 · Cited by 710
From individual to collective chirality in metal nanoparticles
Guerrero-Martínez, A., Alonso-Gómez, J. L., Auguié, B., Cid, M. M., & Liz-Marzán, L. M. (2011) · Nano Today · doi:10.1016/j.nantod.2011.06.003 · Cited by 309
Michaeli, K., Kantor-Uriel, N., Naaman, R., & Waldeck, D. H. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00369a · Cited by 291
Metadata
- Authors
- Yoon, T. P., & Jacobsen, E. N.
- Venue
- Science
- Published
- 2003-03-14
- Volume
- 299
- Issue
- 5613
- Pages
- 1691-1693
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1989807773
- Cited by
- 1,459
- References
- 1
- FWCI
- 31.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yoon, T. P., & Jacobsen, E. N. (2003). Privileged Chiral Catalysts. Science. https://doi.org/10.1126/science.1083622
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
