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Synthesis of Zeolite As Ordered Multicrystal Arrays
Abstract
Zeolites are crystalline nanoporous aluminosilicates widely used in industry. In order for zeolites to find applications as innovative materials, they need to be organized into large two- and three-dimensional (2D and 3D) arrays. We report that uniformly aligned polyurethane films can serve as templates for the synthesis of uniformly aligned 2D and possibly 3D arrays of silicalite-1 crystals, in which the orientations of the crystals are controlled by the nature of the polymers. We propose that the supramolecularly organized organic-inorganic composites that consist of the hydrolyzed organic products and the seed crystals are responsible for this phenomenon.
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Cites
Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
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Wang, S., Liu, G., & Wang, L. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00584 · Cited by 847
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Tao, A., Sinsermsuksakul, P., & Yang, P. (2007) · Nature Nanotechnology · doi:10.1038/nnano.2007.189 · Cited by 615
Surface Chemistry for Molecular Layer Deposition of Organic and Hybrid Organic−Inorganic Polymers
George, S. M., Yoon, B., & Dameron, A. A. (2009) · Accounts of Chemical Research · doi:10.1021/ar800105q · Cited by 377
Metadata
- Authors
- Lee, J. S., Lee, Y.-J., Tae, E. L., Park, Y. S., & Yoon, K. B.
- Venue
- Science
- Published
- 2003-08-08
- Volume
- 301
- Issue
- 5634
- Pages
- 818-821
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2046778260
- Cited by
- 167
- References
- 1
- FWCI
- 7.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lee, J. S., Lee, Y.-J., Tae, E. L., Park, Y. S., & Yoon, K. B. (2003). Synthesis of Zeolite As Ordered Multicrystal Arrays. Science. https://doi.org/10.1126/science.1086441
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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