The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
A Linear, O-Coordinated η 1 -CO 2 Bound to Uranium
Abstract
The electron-rich, six-coordinate tris-aryloxide uranium(III) complex [(( Ad ArO) 3 tacn)U III ] [where ( Ad ArOH) 3 tacn = 1,4,7-tris(3-adamantyl-5- tert -butyl-2-hydroxybenzyl)1,4,7-triazacyclononane] reacts rapidly with CO 2 to yield [(( Ad ArO) 3 tacn)U IV (CO 2 )], a complex in which the CO 2 ligand is linearly coordinated to the metal through its oxygen atom (η 1 -OCO). The latter complex has been crystallographically and spectroscopically characterized. The inequivalent O–C–O bond lengths [1.122 angstroms (Å) for the O–C bond adjacent to uranium and 1.277 Å for the other], considered together with magnetization data and electronic and vibrational spectra, support the following bonding model: U IV =O=C⚫–O – ↔ U IV –O C–O – . In these charge-separated resonance structures, the uranium center is oxidized to uranium(IV) and the CO 2 ligand reduced by one electron.
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Cites
The Global Carbon Cycle: A Test of Our Knowledge of Earth as a System
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The Chemistry of the Actinide Elements: Volume 2
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The Organometallic Chemistry of Carbon Dioxide
Gibson, D. H. (1996) · Chemical Reviews · doi:10.1021/cr940212c · Cited by 622
On the bonding and reactivity of CO2 on metal surfaces
Freund, H.-J., & Messmer, R. P. (1986) · Surface Science · doi:10.1016/0039-6028(86)90580-7 · Cited by 231
Castro-Rodriguez, I., Olsen, K., Gantzel, P., & Meyer, K. (2003) · Journal of the American Chemical Society · doi:10.1021/ja028342n · Cited by 210
Self-citationGibson, D. H. (1999) · Coordination Chemistry Reviews · doi:10.1016/s0010-8545(99)00021-1 · Cited by 200
Kinetic and crystallographic studies on deacetoxycephalosporin C synthase (DAOCS)
Lee, H. J., Lloyd, M. D., Harlos, K., Clifton, I. J., Baldwin, J. E., & Schofield, C. J. (2001) · Journal of Molecular Biology · doi:10.1006/jmbi.2001.4649 · Cited by 102
Carbon dioxide coordination chemistry. 3. Adducts of carbon dioxide with iridium(I) complexes
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Cited by
Cokoja, M., Bruckmeier, C., Rieger, B., Herrmann, W. A., & Kühn, F. E. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102010 · Cited by 1,624
Manifestations of Noninnocent Ligand Behavior
Kaim, W. (2011) · Inorganic Chemistry · doi:10.1021/ic2003832 · Cited by 498
Fox, A. R., Bart, S. C., Meyer, K., & Cummins, C. C. (2008) · Nature · doi:10.1038/nature07372 · Cited by 451
Self-citationAresta, M., Dibenedetto, A., & Quaranta, E. (2016) · Journal of Catalysis · doi:10.1016/j.jcat.2016.04.003 · Cited by 346
The vitality of uranium molecular chemistry at the dawn of the XXIst century
Ephritikhine, M. (2006) · Dalton Transactions · doi:10.1039/b603463b · Cited by 314
Metadata
- Authors
- Castro-Rodriguez, I., Nakai, H., Zakharov, L. N., Rheingold, A. L., & Meyer, K.
- Venue
- Science
- Published
- 2004-09-17
- Volume
- 305
- Issue
- 5691
- Pages
- 1757-1759
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1975964562
- Cited by
- 362
- References
- 9
- FWCI
- 8.98
- Type
- journal article
- Language
- en
- Open access
- closed
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