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Triple-Bond Reactivity of Diphosphorus Molecules
Abstract
We report a mild method for generating the diphosphorus molecule or its synthetic equivalent in homogeneous solution; the P 2 allotrope of the element phosphorus is normally obtained only under extreme conditions (for example, from P 4 at 1100 kelvin). Diphosphorus is extruded from a niobium complex designed for this purpose and can be trapped efficiently by two equivalents of an organic diene to produce an organodiphosphorus compound. Diphosphorus stabilized by coordination to tungsten pentacarbonyl can be generated similarly at 25°C, and in this stabilized form it still efficiently consumes two organic diene molecules for every diphosphorus unit.
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Cited by
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices
Pang, J., Bachmatiuk, A., Yin, Y., Trzebicka, B., Zhao, L., Fu, L., Mendes, R. G., Gemming, T., Liu, Z., & Rummeli, M. H. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702093 · Cited by 518
P4 Activation by Late-Transition Metal Complexes
Caporali, M., Gonsalvi, L., Rossin, A., & Peruzzini, M. (2010) · Chemical Reviews · doi:10.1021/cr900349u · Cited by 448
Metadata
- Authors
- Piro, N. A., Figueroa, J. S., McKellar, J. T., & Cummins, C. C.
- Venue
- Science
- Published
- 2006-09
- Volume
- 313
- Issue
- 5791
- Pages
- 1276-1279
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2060242565
- Cited by
- 204
- References
- 0
- FWCI
- 12.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Piro, N. A., Figueroa, J. S., McKellar, J. T., & Cummins, C. C. (2006). Triple-Bond Reactivity of Diphosphorus Molecules. Science. https://doi.org/10.1126/science.1129630
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