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Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks
Abstract
An unusually large expansion upon solvent adsorption occurs without apparent bond breaking in the network of a series of isoreticular chromium(III) or iron(III) diarboxylates labeled MIL-88A to D [dicarbox = fumarate (88A); terephthalate (1,4-BDC) (88B); 2,6-naphthalenedicarboxylate (2,6-NDC) (88C); and 4-4′-biphenyldicarboxylate (4-4′-BPDC) (88D)]. This reversible “breathing” motion was analyzed in terms of cell dimensions (extent of breathing), movements within the framework (mechanism of transformation), and the interactions between the guests and the skeleton. In situ techniques show that these flexible solids are highly selective absorbents and that this selectivity is strongly dependent on the nature of the organic linker.
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Cited by
Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications
Lin, Z.-J., Lü, J., Hong, M., & Cao, R. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60483g · Cited by 874
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Induction of chiral porous solids containing only achiral building blocks
Morris, R. E., & Bu, X. (2010) · Nature Chemistry · doi:10.1038/nchem.628 · Cited by 567
Metal–Organic Frameworks for Food Safety
Wang, P.-L., Xie, L.-H., Joseph, E. A., Li, J.-R., Su, X.-O., & Zhou, H.-C. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00257 · Cited by 533
Coudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
Metadata
- Authors
- Serre, C., Mellot-Draznieks, C., Surblé, S., Audebrand, N., Filinchuk, Y., & Férey, G.
- Venue
- Science
- Published
- 2007-03-30
- Volume
- 315
- Issue
- 5820
- Pages
- 1828-1831
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1970048015
- Cited by
- 1,095
- References
- 0
- FWCI
- 42.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- Serre, C., Mellot-Draznieks, C., Surblé, S., Audebrand, N., Filinchuk, Y., & Férey, G. (2007). Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks. Science. https://doi.org/10.1126/science.1137975
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