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Capillary Wrinkling of Floating Thin Polymer Films

Open access
Huang, Jiangshui, Juszkiewicz, Megan, de Jeu, Wim H., Cerda, Enrique, Emrick, Todd, Menon, Narayanan, Russell, Thomas P.·2007·Science

Abstract

A freely floating polymer film, tens of nanometers in thickness, wrinkles under the capillary force exerted by a drop of water placed on its surface. The wrinkling pattern is characterized by the number and length of the wrinkles. The dependence of the number of wrinkles on the elastic properties of the film and on the capillary force exerted by the drop confirms recent theoretical predictions on the selection of a pattern with a well-defined length scale in the wrinkling instability. We combined scaling relations that were developed for the length of the wrinkles with those for the number of wrinkles to construct a metrology for measuring the elasticity and thickness of ultrathin films that relies on no more than a dish of fluid and a low-magnification microscope. We validated this method on polymer films modified by plasticizer. The relaxation of the wrinkles affords a simple method to study the viscoelastic response of ultrathin films.

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Metadata

Authors
Huang, J., Juszkiewicz, M., de Jeu, W. H., Cerda, E., Emrick, T., Menon, N., & Russell, T. P.
Venue
Science
Published
2007-08-03
Volume
317
Issue
5838
Pages
650-653
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2068220247
Cited by
516
References
0
FWCI
55.25
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Capillary Wrinkling of Floating Thin Polymer Films. https://app.cochat.ai/papers/10.1126/science.1144616
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Huang, J., Juszkiewicz, M., de Jeu, W. H., Cerda, E., Emrick, T., Menon, N., & Russell, T. P. (2007). Capillary Wrinkling of Floating Thin Polymer Films. Science. https://doi.org/10.1126/science.1144616

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