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Atomic-Scale Chemical Imaging of Composition and Bonding by Aberration-Corrected Microscopy
Abstract
Using a fifth-order aberration-corrected scanning transmission electron microscope, which provides a factor of 100 increase in signal over an uncorrected instrument, we demonstrated two-dimensional elemental and valence-sensitive imaging at atomic resolution by means of electron energy-loss spectroscopy, with acquisition times of well under a minute (for a 4096-pixel image). Applying this method to the study of a La 0.7 Sr 0.3 MnO 3 /SrTiO 3 multilayer, we found an asymmetry between the chemical intermixing on the manganese-titanium and lanthanum-strontium sublattices. The measured changes in the titanium bonding as the local environment changed allowed us to distinguish chemical interdiffusion from imaging artifacts.
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Cited by
Wang, D., Xin, H. L., Hovden, R., Wang, H., Yu, Y., Muller, D. A., DiSalvo, F. J., & Abruña, H. D. (2013) · Nature Materials · doi:10.1038/nmat3458 · Cited by 2,082
Self-citationAtomic-resolution imaging of oxidation states in manganites
Varela, M., Oxley, M. P., Luo, W., Tao, J., Watanabe, M., Lupini, A. R., Pantelides, S. T., & Pennycook, S. J. (2009) · Physical Review B · doi:10.1103/physrevb.79.085117 · Cited by 320
Metadata
- Authors
- Muller, D. A., Kourkoutis, L. F., Murfitt, M., Song, J. H., Hwang, H. Y., Silcox, J., Dellby, N., & Krivanek, O. L.
- Venue
- Science
- Published
- 2008-02-22
- Volume
- 319
- Issue
- 5866
- Pages
- 1073-1076
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2071410909
- Cited by
- 617
- References
- 0
- FWCI
- 32.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Atomic-Scale Chemical Imaging of Composition and Bonding by Aberration-Corrected Microscopy. https://app.cochat.ai/papers/10.1126/science.1148820
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- Muller, D. A., Kourkoutis, L. F., Murfitt, M., Song, J. H., Hwang, H. Y., Silcox, J., Dellby, N., & Krivanek, O. L. (2008). Atomic-Scale Chemical Imaging of Composition and Bonding by Aberration-Corrected Microscopy. Science. https://doi.org/10.1126/science.1148820
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