The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
Linked Reactivity at Mineral-Water Interfaces Through Bulk Crystal Conduction
Abstract
The semiconducting properties of a wide range of minerals are often ignored in the study of their interfacial geochemical behavior. We show that surface-specific charge density accumulation reactions combined with bulk charge carrier diffusivity create conditions under which interfacial electron transfer reactions at one surface couple with those at another via current flow through the crystal bulk. Specifically, we observed that a chemically induced surface potential gradient across hematite (α-Fe 2 O 3 ) crystals is sufficiently high and the bulk electrical resistivity sufficiently low that dissolution of edge surfaces is linked to simultaneous growth of the crystallographically distinct (001) basal plane. The apparent importance of bulk crystal conduction is likely to be generalizable to a host of naturally abundant semiconducting minerals playing varied key roles in soils, sediments, and the atmosphere.
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Cites
The Iron Oxides: Structure, Properties, Reactions, Occurences and Uses
Cornell, R. M., & Schwertmann, U. (2003) · doi:10.1002/3527602097 · Cited by 4,422
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Charge transport in metal oxides: A theoretical study of hematite α-Fe2O3
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Self-citationStructure and reactivity of the hydrated hematite (0001) surface
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Cited by
Solar Water Splitting: Progress Using Hematite (α‐Fe2O3) Photoelectrodes
Sivula, K., Le Formal, F., & Grätzel, M. (2011) · ChemSusChem · doi:10.1002/cssc.201000416 · Cited by 2,678
Biogeochemical Redox Processes and their Impact on Contaminant Dynamics
Borch, T., Kretzschmar, R., Kappler, A., Cappellen, P. V., Ginder-Vogel, M., Voegelin, A., & Campbell, K. (2010) · Environmental Science & Technology · doi:10.1021/es9026248 · Cited by 1,456
Giant Enhancement of Internal Electric Field Boosting Bulk Charge Separation for Photocatalysis
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Atom Exchange between Aqueous Fe(II) and Goethite: An Fe Isotope Tracer Study
Handler, R. M., Beard, B. L., Johnson, C. M., & Scherer, M. M. (2009) · Environmental Science & Technology · doi:10.1021/es802402m · Cited by 356
Trace element cycling through iron oxide minerals during redox driven dynamic recrystallization
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Metadata
- Authors
- Yanina, S. V., & Rosso, K. M.
- Venue
- Science
- Published
- 2008-04-11
- Volume
- 320
- Issue
- 5873
- Pages
- 218-222
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2090892825
- Cited by
- 381
- References
- 21
- FWCI
- 12.07
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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