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Molecular Layering of Fluorinated Ionic Liquids at a Charged Sapphire (0001) Surface
Abstract
Room-temperature ionic liquids (RTILs) are promising candidates for a broad range of “green” applications, for which their interaction with solid surfaces plays a crucial role. In this high-energy x-ray reflectivity study, the temperature-dependent structures of three ionic liquids with the tris(pentafluoroethyl)trifluorophosphate anion in contact with a charged sapphire substrate were investigated with submolecular resolution. All three RTILs show strong interfacial layering, starting with a cation layer at the substrate and decaying exponentially into the bulk liquid. The observed decay length and layering period point to an interfacial ordering mechanism, akin to the charge inversion effect, which is suggested to originate from strong correlations between the unscreened ions. The observed layering is expected to be a generic feature of RTILs at charged interfaces.
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Citations
Cites
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007) · Science · doi:10.1126/science.1141199 · Cited by 1,997
Cited by
Structure and Nanostructure in Ionic Liquids
Hayes, R., Warr, G. G., & Atkin, R. (2015) · Chemical Reviews · doi:10.1021/cr500411q · Cited by 2,293
Double Layer in Ionic Liquids: Overscreening versus Crowding
Bazant, M. Z., Storey, B. D., & Kornyshev, A. A. (2011) · Physical Review Letters · doi:10.1103/physrevlett.106.046102 · Cited by 1,098
Zhang, S., Zhang, J., Zhang, Y., & Deng, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00509 · Cited by 659
Energy applications of ionic liquids
Wishart, J. F. (2009) · Energy & Environmental Science · doi:10.1039/b906273d · Cited by 502
Probing Liquid/Solid Interfaces at the Molecular Level
Zaera, F. (2012) · Chemical Reviews · doi:10.1021/cr2002068 · Cited by 458
Metadata
- Authors
- Mezger, M., Schröder, H., Reichert, H., Schramm, S., Okasinski, J. S., Schöder, S., Honkimäki, V., Deutsch, M., Ocko, B. M., Ralston, J., Rohwerder, M., Stratmann, M., & Dosch, H.
- Venue
- Science
- Published
- 2008-10-17
- Volume
- 322
- Issue
- 5900
- Pages
- 424-428
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1988598239
- Cited by
- 653
- References
- 1
- FWCI
- 12.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mezger, M., Schröder, H., Reichert, H., Schramm, S., Okasinski, J. S., Schöder, S., Honkimäki, V., Deutsch, M., Ocko, B. M., Ralston, J., Rohwerder, M., Stratmann, M., & Dosch, H. (2008). Molecular Layering of Fluorinated Ionic Liquids at a Charged Sapphire (0001) Surface. Science. https://doi.org/10.1126/science.1164502
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
