The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Solid Nanoparticles that Catalyze Biofuel Upgrade Reactions at the Water/Oil Interface
Abstract
Metal in the Middle: Biphasic reaction mixtures allow the isolation of sensitive products, which can form in one solvent and then shift rapidly into another, protected from side reactions and interfering by-products. However, ensuring that catalysts remain in the proper phase can be challenging, and surfactants added to induce efficient mixing often prove difficult to separate from the product stream. Crossley et al. (p. 68 ; see the Perspective by Cole-Hamilton ) tackle these issues by preparing easily recoverable amphiphilic nanoparticles that simultaneously stabilize aqueous-organic emulsions and catalyze organic reactions. The particles combine hydrophobic nanotubes with hydrophilic oxides, causing them to accumulate at water-hydrocarbon interfaces. Depositing palladium on specific portions of the particles' surfaces thus localizes the metal in one or both phases, facilitating hydrogenation of several compounds of interest in biofuel refining.
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Cites
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
Mohan, D., Pittman, C. U., & Steele, P. H. (2006) · Energy & Fuels · doi:10.1021/ef0502397 · Cited by 5,663
Cited by
Review of fast pyrolysis of biomass and product upgrading
Bridgwater, A. V. (2012) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2011.01.048 · Cited by 4,856
Catalytic conversion of lignocellulosic biomass into chemicals and fuels
Deng, W., Feng, Y., Fu, J., Guo, H., Guo, Y., Han, B., Jiang, Z., Kong, L., Li, C., Liu, H., et al. (2023) · Green Energy & Environment · doi:10.1016/j.gee.2022.07.003 · Cited by 854
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Ketonization of Carboxylic Acids: Mechanisms, Catalysts, and Implications for Biomass Conversion
Pham, T. N., Sooknoi, T., Crossley, S. P., & Resasco, D. E. (2013) · ACS Catalysis · doi:10.1021/cs400501h · Cited by 451
Self-citationNanoscale Advances in Catalysis and Energy Applications
Li, Y., & Somorjai, G. A. (2010) · Nano Letters · doi:10.1021/nl101807g · Cited by 441
Metadata
- Authors
- Crossley, S., Faria, J., Shen, M., & Resasco, D. E.
- Venue
- Science
- Published
- 2010-01
- Volume
- 327
- Issue
- 5961
- Pages
- 68-72
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2033342037
- Cited by
- 809
- References
- 1
- FWCI
- 16.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Crossley, S., Faria, J., Shen, M., & Resasco, D. E. (2010). Solid Nanoparticles that Catalyze Biofuel Upgrade Reactions at the Water/Oil Interface. Science. https://doi.org/10.1126/science.1180769
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
