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Design of Polymethine Dyes with Large Third-Order Optical Nonlinearities and Loss Figures of Merit

Hales, Joel M., Matichak, Jonathan, Barlow, Stephen, Ohira, Shino, Yesudas, Kada, Brédas, Jean-Luc, Perry, Joseph W., Marder, Seth R.·2010·Science

Abstract

Dying by Design: To make optical-switching applications a reality, losses from scattering and other absorption processes have to be minimized. Hales et al. (p. 1485 , published online 18 February; see the Perspective by Haque and Nelson ) present a strategy to explore the refraction and absorption properties of a group of cyanine dyes for designing materials that have properties corresponding to technologically interesting telecommunications windows. The optical properties of the cyanine molecule was controlled by adding heavy chalcogen atoms (selenium) into the end groups of the molecular structure. While producing a series of molecules meeting criteria for feasible application, the work also demonstrates a route to improve the performance of nonlinear optical materials.

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Authors
Hales, J. M., Matichak, J., Barlow, S., Ohira, S., Yesudas, K., Brédas, J.-L., Perry, J. W., & Marder, S. R.
Venue
Science
Published
2010-03-19
Volume
327
Issue
5972
Pages
1485-1488
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2093272595
Cited by
363
References
0
FWCI
12.50
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Design of Polymethine Dyes with Large Third-Order Optical Nonlinearities and Loss Figures of Merit. https://app.cochat.ai/papers/10.1126/science.1185117
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Hales, J. M., Matichak, J., Barlow, S., Ohira, S., Yesudas, K., Brédas, J.-L., Perry, J. W., & Marder, S. R. (2010). Design of Polymethine Dyes with Large Third-Order Optical Nonlinearities and Loss Figures of Merit. Science. https://doi.org/10.1126/science.1185117

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