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Anomalous Strength Characteristics of Tilt Grain Boundaries in Graphene
Open accessAbstract
Perfect Imperfections: Graphene is composed of six-atom rings, but will include a number of five- and seven-atom rings as defects. Using simulations, Grantab et al. (p. 946 ) show that more defects do not necessarily lead to greater deterioration of mechanical properties. Mismatches caused by differences in the orientation of neighboring crystals are divided into low- and high-angle grain boundaries, and typically it is the lower-angle boundaries that are stronger. In graphene, by contrast, the larger-angle boundaries, which consist of higher-defect densities, are better able to accommodate the strain and prevent failure that originates in the breakup of the seven-member graphene rings. This suggests ways for synthesizing imperfect graphene sheets that will have mechanical properties that are close to those of perfect graphene.
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Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
Graphene: Status and Prospects
Geim, A. K. (2009) · Science · doi:10.1126/science.1158877 · Cited by 13,942
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Metadata
- Authors
- Grantab, R., Shenoy, V. B., & Ruoff, R. S.
- Venue
- Science
- Published
- 2010-11-12
- Volume
- 330
- Issue
- 6006
- Pages
- 946-948
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2124557609
- Cited by
- 829
- References
- 2
- FWCI
- 27.34
- Type
- journal article
- Language
- en
- Open access
- green
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