The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin
Abstract
Fluorine's Smooth Introduction: Carbon-fluorine bonds are emerging as increasingly versatile constituents of drugs, agrochemicals, and positron emission tomography tracers. Elemental F 2 gas is in principle an efficient reagent for their preparation, but its extreme reactivity requires special handling precautions. Substantial research has therefore focused on promoting selective reactivity of more conveniently handled fluoride ion salts. Liu et al. (p. 1322 ) present a manganese catalyst that transfers fluoride to a range of hydrocarbons in conjunction with a hypervalent iodine-based oxidant. Mechanistic studies implicate a manganese difluoride intermediate that reacts with alkyl radicals generated by a preceding manganese oxo.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
Self-consistent molecular orbital methods. XX. A basis set for correlated wave functions
Krishnan, R., Binkley, J. S., Seeger, R., & Pople, J. A. (1980) · The Journal of Chemical Physics · doi:10.1063/1.438955 · Cited by 17,772
A new mixing of Hartree–Fock and local density-functional theories
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464304 · Cited by 16,515
Reactive oxygen species have a causal role in multiple forms of insulin resistance
Houstis, N., Rosen, E. D., & Lander, E. S. (2006) · Nature · doi:10.1038/nature04634 · Cited by 2,525
Herceptin acts as an anti-angiogenic cocktail
Izumi, Y., Xu, L., di Tomaso, E., Fukumura, D., & Jain, R. K. (2002) · Nature · doi:10.1038/416279b · Cited by 623
Cited by
Late-stage C–H functionalization offers new opportunities in drug discovery
Guillemard, L., Kaplaneris, N., Ackermann, L., & Johansson, M. J. (2021) · Nature Reviews Chemistry · doi:10.1038/s41570-021-00300-6 · Cited by 837
Synthetic Applications of Proton-Coupled Electron Transfer
Gentry, E. C., & Knowles, R. R. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00272 · Cited by 773
Transition‐Metal‐Catalyzed Selective Functionalization of C(sp3)−H Bonds in Natural Products
Karimov, R. R., & Hartwig, J. F. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710330 · Cited by 341
Metadata
- Authors
- Liu, W., Huang, X., Cheng, M.-J., Nielsen, R. J., Goddard, W. A., & Groves, J. T.
- Venue
- Science
- Published
- 2012-09-14
- Volume
- 337
- Issue
- 6100
- Pages
- 1322-1325
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1977262764
- Cited by
- 566
- References
- 5
- FWCI
- 28.74
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin. https://app.cochat.ai/papers/10.1126/science.1222327
- The paper
- Liu, W., Huang, X., Cheng, M.-J., Nielsen, R. J., Goddard, W. A., & Groves, J. T. (2012). Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin. Science. https://doi.org/10.1126/science.1222327
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
