The DOI matches its Crossref record.
An Efficient Polymer Molecular Sieve for Membrane Gas Separations
Open accessAbstract
Bicyclic Bridge to Improvement: Polymers of intrinsic microporosity are a recently developed class of contorted rigid glassy ladderlike polymers having very high free volume (open internal spaces). The intrinsic porosity of these materials has made them of interest for ultrahigh permeability gas separation membranes. However, while the polymers show good gas permeability, they have only moderate gas selectivity. Carta et al. (p. 303 ; see the Perspective by Guiver and Lee ) hypothesized that if they could replace the dioxin-like rings in their polymers with stiffer bridged bicyclic rings, they could improve the membrane properties of the polymer. By exploiting reactions connected to the formation of Tröger's base to form the multiple covalent bonds needed to make the bicyclic rings, the resulting polymers showed significantly improved selectivity and permeability.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Metal–organic frameworks for membrane-based separations
Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Nonporous Adaptive Crystals of Pillararenes
Jie, K., Zhou, Y., Li, E., & Huang, F. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00255 · Cited by 533
Anion exchange polyelectrolytes for membranes and ionomers
Chen, N., & Lee, Y. M. (2021) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101345 · Cited by 445
Polymer Networks: From Plastics and Gels to Porous Frameworks
Gu, Y., Zhao, J., & Johnson, J. A. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201902900 · Cited by 388
Metadata
- Authors
- Carta, M., Malpass-Evans, R., Croad, M., Rogan, Y., Jansen, J. C., Bernardo, P., Bazzarelli, F., & McKeown, N. B.
- Venue
- Science
- Published
- 2013-01-18
- Volume
- 339
- Issue
- 6117
- Pages
- 303-307
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2023562556
- Cited by
- 1,119
- References
- 0
- FWCI
- 108.93
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: An Efficient Polymer Molecular Sieve for Membrane Gas Separations. https://app.cochat.ai/papers/10.1126/science.1228032
- The paper
- Carta, M., Malpass-Evans, R., Croad, M., Rogan, Y., Jansen, J. C., Bernardo, P., Bazzarelli, F., & McKeown, N. B. (2013). An Efficient Polymer Molecular Sieve for Membrane Gas Separations. Science. https://doi.org/10.1126/science.1228032
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
