The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy
Open accessAbstract
From C=C to C=O: The palladium-catalyzed Heck reaction is widely used to form carbon-carbon bonds between aryl rings and olefins, after which elimination of a hydrogen atom restores the olefin's double bond. Werner et al. (p. 1455 ; see the Perspective by Gilbertson ) present a variant of this reaction in which a hydrogen atom is instead lost from an alcohol center elsewhere in the molecule, yielding a ketone and a chiral center where the arene is bound. The process is highly enantioselective and also versatile: The alcohol can be sited one, two, or even three carbons away from the olefin.
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Citations
Cites
The Heck Reaction as a Sharpening Stone of Palladium Catalysis
Beletskaya, I. P., & Cheprakov, A. V. (2000) · Chemical Reviews · doi:10.1021/cr9903048 · Cited by 3,902
Redox Economy in Organic Synthesis
Burns, N. Z., Baran, P. S., & Hoffmann, R. W. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806086 · Cited by 769
Shibasaki, M., Vogl, E. M., & Ohshima, T. (2004) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200404203 · Cited by 327
Multidimensional steric parameters in the analysis of asymmetric catalytic reactions
Harper, K. C., Bess, E. N., & Sigman, M. S. (2012) · Nature Chemistry · doi:10.1038/nchem.1297 · Cited by 294
Self-citationSigman, M. S., & Werner, E. W. (2012) · Accounts of Chemical Research · doi:10.1021/ar200236v · Cited by 221
Self-citationHarper, K. C., & Sigman, M. S. (2011) · Science · doi:10.1126/science.1206997 · Cited by 215
Self-citationJensen, K. H., Webb, J. D., & Sigman, M. S. (2010) · Journal of the American Chemical Society · doi:10.1021/ja108106h · Cited by 170
Self-citationDjakovitch, L., Wagner, M., Hartung, C. G., Beller, M., & Köhler, K. (2004) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2004.04.035 · Cited by 115
Cited by
Recent Development of Aryl Diazonium Chemistry for the Derivatization of Aromatic Compounds
Mo, F., Qiu, D., Zhang, L., & Wang, J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01030 · Cited by 361
The Development of Multidimensional Analysis Tools for Asymmetric Catalysis and Beyond
Sigman, M. S., Harper, K. C., Bess, E. N., & Milo, A. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.6b00194 · Cited by 357
Self-citationZahrt, A. F., Athavale, S. V., & Denmark, S. E. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00425 · Cited by 212
Metadata
- Authors
- Werner, E. W., Mei, T.-S., Burckle, A. J., & Sigman, M. S.
- Venue
- Science
- Published
- 2012-12-14
- Volume
- 338
- Issue
- 6113
- Pages
- 1455-1458
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1992002089
- Cited by
- 477
- References
- 8
- FWCI
- 11.96
- Type
- journal article
- Language
- en
- Open access
- green
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