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Probing the transition state region in catalytic CO oxidation on Ru
Abstract
Catching CO oxidation: Details of the transition state that forms as carbon monoxide (CO) adsorbed on a ruthenium surface is oxidized to CO 2 have been revealed by ultrafast excitation and probe methods. Öström et al. initiated the reaction between CO and adsorbed oxygen atoms with laser pulses that rapidly heated the surface and then probed the changes in electronic structure with oxygen x-ray absorption spectroscopy. They observed transition-state configurations that are consistent with density functional theory and a quantum oscillator model. Science , this issue p. 978
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Femtosecond x-ray spectroscopy of an electrocyclic ring-opening reaction
Attar, A. R., Bhattacherjee, A., Pemmaraju, C. D., Schnorr, K., Closser, K. D., Prendergast, D., & Leone, S. R. (2017) · Science · doi:10.1126/science.aaj2198 · Cited by 338
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Zhang, Y., Lin, Y., Duan, T., & Song, L. (2021) · Materials Today · doi:10.1016/j.mattod.2021.02.004 · Cited by 267
An, J., Wang, Y., Lu, J., Zhang, J., Zhang, Z., Xu, S., Liu, X., Zhang, T., Gocyla, M., Heggen, M., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01742 · Cited by 258
Metadata
- Authors
- Öström, H., Öberg, H., Xin, H., LaRue, J., Beye, M., Dell’Angela, M., Gladh, J., Ng, M. L., Sellberg, J. A., Kaya, S., Mercurio, G., Nordlund, D., Hantschmann, M., Hieke, F., Kühn, D., Schlotter, W. F., Dakovski, G. L., Turner, J. J., Minitti, M. P., Mitra, A., Moeller, S. P., Föhlisch, A., Wolf, M., Wurth, W., Persson, M., Nørskov, J. K., Abild-Pedersen, F., Ogasawara, H., Pettersson, L. G. M., & Nilsson, A.
- Venue
- Science
- Published
- 2015-02-27
- Volume
- 347
- Issue
- 6225
- Pages
- 978-982
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2147234492
- Cited by
- 237
- References
- 0
- FWCI
- 15.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Öström, H., Öberg, H., Xin, H., LaRue, J., Beye, M., Dell’Angela, M., Gladh, J., Ng, M. L., Sellberg, J. A., Kaya, S., Mercurio, G., Nordlund, D., Hantschmann, M., Hieke, F., Kühn, D., Schlotter, W. F., Dakovski, G. L., Turner, J. J., Minitti, M. P., . . . Nilsson, A. (2015). Probing the transition state region in catalytic CO oxidation on Ru. Science. https://doi.org/10.1126/science.1261747
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.