The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Calcium Carbonate Concretions Formed by the Decomposition of Organic Matter
Abstract
Bacterial decomposition of butterfish and smelts in small sealed jars containing seawater and other solutions, for periods ranging from 65 to 205 days, results in a large increase in concentrations of dissolved bicarbonate, carbonate, and ammonia (plus volatile amines). Accompanying this is a rise in pH and the precipitation of Ca ++ ion from solution. The Ca ++ is not precipitated as CaCO 3 but instead as a mixture of calcium fatty acid salts or soaps with from 14 to 18 carbon atoms. This can be explained by the thermodynamic instability of CaCO 3 relative to Ca soaps in the presence of excess free fatty acid. It is suggested that some ancient CaCO 3 concretions, especially those enclosing fossils of soft-bodied organisms, may have formed rapidly after death in the form of natural Ca soap (adipocere) which was later converted to CaCO 3 .
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Cites
A postulated role of fatty acids in petroleum formation
Cooper, J. E., & Bray, E. E. (1963) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(63)90093-0 · Cited by 313
THE SOLUBILITIES OF THE NORMAL SATURATED FATTY ACIDS
RALSTON, A. W., & HOERR, C. W. (1942) · The Journal of Organic Chemistry · doi:10.1021/jo01200a013 · Cited by 214
THE SOLUBILITIES OF THE NORMAL SATURATED FATTY ACIDS. III
HOERR, C. W., SEDGWICK, R. S., & RALSTON, A. W. (1946) · The Journal of Organic Chemistry · doi:10.1021/jo01175a025 · Cited by 194
Twenhofel, W. H. (1933) · The Journal of Physical Chemistry · doi:10.1021/j150344a017 · Cited by 158
Diagenesis of metabolites and a discussion of the origin of petroleum hydrocarbons
Breger, I. A. (1960) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(60)90036-3 · Cited by 69
Carbon and oxygen isotope ratios in diagenetic carbonates from marine sediments
Hodgson, W. A. (1966) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(66)90121-9 · Cited by 57
Irani, R. R., & Callis, C. F. (1960) · The Journal of Physical Chemistry · doi:10.1021/j100840a034 · Cited by 33
Composition of Combustible Concretions of the Alewife, Alosa pseudoharengus
Sondheimer, E., Dence, W. A., MATTICK, L. R., & Silverman, S. R. (1966) · Science · doi:10.1126/science.152.3719.221 · Cited by 14
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Metadata
- Authors
- Berner, R. A.
- Venue
- Science
- Published
- 1968-01-12
- Volume
- 159
- Issue
- 3811
- Pages
- 195-197
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1983214896
- Cited by
- 253
- References
- 8
- FWCI
- 14.93
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
