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Quadratic Elongation: A Quantitative Measure of Distortion in Coordination Polyhedra
Abstract
Quadratic elongation and the variance of bond angles are linearly correlated for distorted octahedral and tetrachedral coordination complexes, both of which show variations in bond length and bond angle. The quadratic elongation is dimensionless, giving a quantitative measure of polyhedral distortion which is independent of the effective size of the polyhedron.
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Cited by
Du, K.-Z., Tu, Q., Zhang, X., Han, Q., Liu, J., Zauscher, S., & Mitzi, D. B. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b01094 · Cited by 587
Reduced-dimensional perovskite photovoltaics with homogeneous energy landscape
He, T., Li, S., Jiang, Y., Qin, C., Cui, M., Qiao, L., Xu, H., Yang, J., Long, R., Wang, H., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-15451-1 · Cited by 325
Chukanovite, Fe2(CO3)(OH)2, a new mineral from the weathered iron meteorite Dronino
Pekov, I. V., Perchiazzi, N., Merlino, S., Kalachev, V. N., Merlini, M., & Zadov, A. E. (2007) · European Journal of Mineralogy · doi:10.1127/0935-1221/2007/0019-1767 · Cited by 98
Learn-and-Match Molecular Cations for Perovskites
Park, H., Mall, R., Alharbi, F. H., Sanvito, S., Tabet, N., Bensmail, H., & El-Mellouhi, F. (2019) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.9b06208 · Cited by 50
Chiral indices of crystalline surfaces as a measure of enantioselective potential
Downs, R. T., & Hazen, R. M. (2004) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/j.molcata.2004.03.026 · Cited by 49
Metadata
- Authors
- Robinson, K., Gibbs, G. V., & Ribbe, P. H.
- Venue
- Science
- Published
- 1971-05-07
- Volume
- 172
- Issue
- 3983
- Pages
- 567-570
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2027581929
- Cited by
- 2,160
- References
- 0
- FWCI
- 4.19
- Type
- journal article
- Language
- en
- Open access
- closed
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- Robinson, K., Gibbs, G. V., & Ribbe, P. H. (1971). Quadratic Elongation: A Quantitative Measure of Distortion in Coordination Polyhedra. Science. https://doi.org/10.1126/science.172.3983.567
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
