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Normal Atmosphere: Large Radical and Formaldehyde Concentrations Predicted
Abstract
A steady-state model of the normal (unpolluted) surface atmosphere predicts a daytime concentration of hydroxyl, hydroperoxyl, and methylperoxyl radicals approaching 5 × 10 8 molecules per cubic centimeter and a formaldehyde concentration of 5 × 10 10 molecules per cubic centimeter or 2 parts per billion. A radical chain reaction is proposed for the rapid removal of carbon monoxide, leading to a carbon monoxide lifetime as low as 0.2 year in the surface atmosphere.
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Citations
Cited by
Changing concentration, lifetime and climate forcing of atmospheric methane
LELIEVELD, J., CRUTZEN, P. J., & DENTENER, F. J. (1998) · Tellus B · doi:10.1034/j.1600-0889.1998.t01-1-00002.x · Cited by 733
High winter ozone pollution from carbonyl photolysis in an oil and gas basin
Edwards, P. M., Brown, S. S., Roberts, J. M., Ahmadov, R., Banta, R. M., deGouw, J. A., Dubé, W. P., Field, R. A., Flynn, J. H., Gilman, J. B., et al. (2014) · Nature · doi:10.1038/nature13767 · Cited by 404
Analysis of present-day and future OH and methane lifetime in the ACCMIP simulations
Voulgarakis, A., Naik, V., Lamarque, J.-F., Shindell, D. T., Young, P. J., Prather, M. J., Wild, O., Field, R. D., Bergmann, D., Cameron-Smith, P., et al. (2013) · Atmospheric chemistry and physics · doi:10.5194/acp-13-2563-2013 · Cited by 324
Tropospheric chemical composition measurements in Brazil during the dry season
Crutzen, P. J., Delany, A. C., Greenberg, J., Haagenson, P., Heidt, L., Lueb, R., Pollock, W., Seiler, W., Wartburg, A., & Zimmerman, P. (1985) · Journal of Atmospheric Chemistry · doi:10.1007/bf00051075 · Cited by 384
Naik, V., Voulgarakis, A., Fiore, A. M., Horowitz, L. W., Lamarque, J.-F., Lin, M., Prather, M. J., Young, P. J., Bergmann, D., Cameron-Smith, P. J., et al. (2013) · Atmospheric Chemistry and Physics · doi:10.5194/acp-13-5277-2013 · Cited by 371
Metadata
- Authors
- Levy, H.
- Venue
- Science
- Published
- 1971-07-09
- Volume
- 173
- Issue
- 3992
- Pages
- 141-143
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1978153810
- Cited by
- 1,076
- References
- 0
- FWCI
- 27.28
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Normal Atmosphere: Large Radical and Formaldehyde Concentrations Predicted. https://app.cochat.ai/papers/10.1126/science.173.3992.141
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- Levy, H. (1971). Normal Atmosphere: Large Radical and Formaldehyde Concentrations Predicted. Science. https://doi.org/10.1126/science.173.3992.141
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.