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Free-Radical Oxidants in Natural Waters
Abstract
Photooxidation of cumene (isopropylbenzene) and pyridine in dilute solution in natural waters gives products characteristic of reactions with alkylperoxy (RO 2 ⋅) and hydroxyl (HO⋅) radicals. On the basis of the rates of formation of the products, the average concentrations of RO 2 ⋅ and HO⋅ are estimated to be about 10 -9 and 10 -17 mole per liter, respectively. The concentration of RO 2 ⋅ is large enough that, for some classes of reactive chemicals, oxidation can be an important process in natural waters.
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Citations
Cited by
Determination of photochemically produced hydroxyl radicals in seawater and freshwater
Zhou, X., & Mopper, K. (1990) · Marine Chemistry · doi:10.1016/0304-4203(90)90062-h · Cited by 362
Pesticide Photolysis in Prairie Potholes: Probing Photosensitized Processes
Zeng, T., & Arnold, W. A. (2013) · Environmental Science & Technology · doi:10.1021/es3030808 · Cited by 273
Lam, M. W., Tantuco, K., & Mabury, S. A. (2003) · Environmental Science & Technology · doi:10.1021/es025902+ · Cited by 266
Nguyen, T. V., Reinhard, M., & Gin, K. Y.-H. (2013) · Water Research · doi:10.1016/j.watres.2013.01.047 · Cited by 34
Metadata
- Authors
- Mill, T., Hendry, D. G., & Richardson, H.
- Venue
- Science
- Published
- 1980-02-22
- Volume
- 207
- Issue
- 4433
- Pages
- 886-887
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2069280694
- Cited by
- 228
- References
- 0
- FWCI
- 27.03
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Free-Radical Oxidants in Natural Waters. https://app.cochat.ai/papers/10.1126/science.207.4433.886
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- Mill, T., Hendry, D. G., & Richardson, H. (1980). Free-Radical Oxidants in Natural Waters. Science. https://doi.org/10.1126/science.207.4433.886
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.