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Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina
Abstract
This work demonstrates the practicality of forming two self-assembled monolayers (SAMs), independently but simultaneously, by adsorption of two different adsorbates from a common solution onto a substrate exposing two different materials at its surface. The experimental procedure and the degree of independence achieved in the resulting SAMs are illustrated by examination of monolayers obtained by adsorption of alkanethiols on gold and alkane carboxylic acids on alumina. This procedure provides a method for modifying the surface characteristics of microlithographically generated patterns and offers a versatile technique for controlling solid-vapor and solid-liquid interfacial properties in systems having patterns with dimensions of the order of 1 micrometer.
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Cites
Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Cited by
Yah, W. O., Takahara, A., & Lvov, Y. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210258y · Cited by 429
Dobson, K. D., & McQuillan, A. J. (1999) · Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy · doi:10.1016/s1386-1425(98)00303-5 · Cited by 280
Schmitt, L., Ludwig, M., Gaub, H. E., & Tampé, R. (2000) · Biophysical Journal · doi:10.1016/s0006-3495(00)76863-9 · Cited by 171
Metadata
- Authors
- Laibinis, P. E., Hickman, J. J., Wrighton, M. S., & Whitesides, G. M.
- Venue
- Science
- Published
- 1989-08-25
- Volume
- 245
- Issue
- 4920
- Pages
- 845-847
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2055810796
- Cited by
- 337
- References
- 1
- FWCI
- 9.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Laibinis, P. E., Hickman, J. J., Wrighton, M. S., & Whitesides, G. M. (1989). Orthogonal Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic Acids on Alumina. Science. https://doi.org/10.1126/science.245.4920.845
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
