The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Synthesis of Fluoropolymers in Supercritical Carbon Dioxide
Abstract
Fluoropolymers are used in many technologically demanding applications because of their balance of high-performance properties. A significant impediment to the synthesis of variants of commercially available amorphous fluoropolymers is their general insolubility in most solvents except chlorofluorocarbons (CFCs). The environmental concerns about CFCs can be circumvented by preparing these technologically important materials in supercritical fluids. The homogeneous solution polymerization of highly fluorinated acrylic monomers can be achieved in supercritical carbon dioxide by using free radical methods. In addition, detailed decomposition rates and efficiency factors were measured for azobisisobutyronitrile in supercritical carbon dioxide and were compared to those obtained with conventional liquid solvents.
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Odian, G. (2004) · doi:10.1002/047147875x · Cited by 7,158
Cited by
An Earth-like numerical dynamo model
Kuang, W., & Bloxham, J. (1997) · Nature · doi:10.1038/38712 · Cited by 441
Metadata
- Authors
- DeSimone, J. M., Guan, Z., & Elsbernd, C. S.
- Venue
- Science
- Published
- 1992-08-14
- Volume
- 257
- Issue
- 5072
- Pages
- 945-947
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2085667513
- Cited by
- 853
- References
- 1
- FWCI
- 11.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- DeSimone, J. M., Guan, Z., & Elsbernd, C. S. (1992). Synthesis of Fluoropolymers in Supercritical Carbon Dioxide. Science. https://doi.org/10.1126/science.257.5072.945
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
