The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
New Phases of C 60 Synthesized at High Pressure
Abstract
The fullerene C 60 can be converted into two different structures by high pressure and temperature. They are metastable and revert to pristine C 60 on reheating to 300°C at ambient pressure. For synthesis temperatures between 300° and 400°C and pressures of 5 gigapascals, a nominal face-centered-cubic structure is produced with a lattice parameter a o = 13.6 angstroms. When treated at 500° to 800°C at the same pressure, C 60 transforms into a rhombohedral structure with hexagonal lattice parameters of a o = 9.22 angstroms and c o = 24.6 angstroms. The intermolecular distance is small enough that a chemical bond can form, in accord with the reduced solubility of the pressure-induced phases. Infrared, Raman, and nuclear magnetic resonance studies show a drastic reduction of icosahedral symmetry, as might occur if the C 60 molecules are linked.
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Citations
Cites
Photoinduced Polymerization of Solid C 60 Films
Rao, A. M., Zhou, P., Wang, K., Hager, G. T., Holden, J. M., Wang, Y., Lee, W. T., Bi, X.-X., Eklund, P. C., Cornett, D. S., et al. (1993) · Science · doi:10.1126/science.259.5097.955 · Cited by 1,139
Solubility of fullerene (C60) in a variety of solvents
Ruoff, R. S., Tse, D. S., Malhotra, R., & Lorents, D. C. (1993) · The Journal of Physical Chemistry · doi:10.1021/j100115a049 · Cited by 1,087
Giant vibrational resonances in A6 C60 compounds
Fu, K.-J., Karney, W. L., Chapman, O. L., Huang, S., Kaner, R. B., Diederich, F., Holczer, K., & Whetten, R. L. (1992) · Physical review. B, Condensed matter · doi:10.1103/physrevb.46.1937 · Cited by 99
Cited by
Georgakilas, V., Perman, J. A., Tucek, J., & Zboril, R. (2015) · Chemical Reviews · doi:10.1021/cr500304f · Cited by 2,147
Two‐Dimensional Polymers: Just a Dream of Synthetic Chemists?
Sakamoto, J., van Heijst, J., Lukin, O., & Schlüter, A. D. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200801863 · Cited by 734
Makarova, T. L., Sundqvist, B., Höhne, R., Esquinazi, P., Kopelevich, Y., Scharff, P., Davydov, V. A., Kashevarova, L. S., & Rakhmanina, A. V. (2001) · Nature · doi:10.1038/35099527 · Cited by 544
RetractedPolymers containing fullerene or carbon nanotube structures
Wang, C., Guo, Z.-X., Fu, S., Wu, W., & Zhu, D. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.08.001 · Cited by 470
Solvent‐Free Carbon‐Carbon Bond Formations in Ball Mills
Rodríguez, B., Bruckmann, A., Rantanen, T., & Bolm, C. (2007) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200700252 · Cited by 379
Metadata
- Authors
- Iwasa, Y., Arima, T., Fleming, R. M., Siegrist, T., Zhou, O., Haddon, R. C., Rothberg, L. J., Lyons, K. B., Carter, H. L., Hebard, A. F., Tycko, R., Dabbagh, G., Krajewski, J. J., Thomas, G. A., & Yagi, T.
- Venue
- Science
- Published
- 1994-06-10
- Volume
- 264
- Issue
- 5165
- Pages
- 1570-1572
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2048165053
- Cited by
- 674
- References
- 3
- FWCI
- 32.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Iwasa, Y., Arima, T., Fleming, R. M., Siegrist, T., Zhou, O., Haddon, R. C., Rothberg, L. J., Lyons, K. B., Carter, H. L., Hebard, A. F., Tycko, R., Dabbagh, G., Krajewski, J. J., Thomas, G. A., & Yagi, T. (1994). New Phases of C 60 Synthesized at High Pressure. Science. https://doi.org/10.1126/science.264.5165.1570
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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