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Growth and Sintering of Fullerene Nanotubes
Abstract
Carbon nanotubes produced in arcs have been found to have the form of multiwalled fullerenes, at least over short lengths. Sintering of the tubes to each other is the predominant source of defects that limit the utility of these otherwise perfect fullerene structures. The use of a water-cooled copper cathode minimized such defects, permitting nanotubes longer than 40 micrometers to be attached to macroscopic electrodes and extracted from the bulk deposit. A detailed mechanism that features the high electric field at (and field-emission from) open nanotube tips exposed to the arc plasma, and consequent positive feedback effects from the neutral gas and plasma, is proposed for tube growth in such arcs.
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Citations
Cited by
Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes
Wong, E. W., Sheehan, P. E., & Lieber, C. M. (1997) · Science · doi:10.1126/science.277.5334.1971 · Cited by 4,810
Chemistry and Physics in One Dimension: Synthesis and Properties of Nanowires and Nanotubes
Hu, J., Odom, T. W., & Lieber, C. M. (1999) · Accounts of Chemical Research · doi:10.1021/ar9700365 · Cited by 3,338
Andersen, S. M., Borghei, M., Dhiman, R., Ruiz, V., Kauppinen, E., & Skou, E. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp501088d · Cited by 55
Metadata
- Authors
- Colbert, D. T., Zhang, J., McClure, S. M., Nikolaev, P., Chen, Z., Hafner, J. H., Owens, D. W., Kotula, P. G., Carter, C. B., Weaver, J. H., Rinzler, A. G., & Smalley, R. E.
- Venue
- Science
- Published
- 1994-11-18
- Volume
- 266
- Issue
- 5188
- Pages
- 1218-1222
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1978864750
- Cited by
- 333
- References
- 0
- FWCI
- 19.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Colbert, D. T., Zhang, J., McClure, S. M., Nikolaev, P., Chen, Z., Hafner, J. H., Owens, D. W., Kotula, P. G., Carter, C. B., Weaver, J. H., Rinzler, A. G., & Smalley, R. E. (1994). Growth and Sintering of Fullerene Nanotubes. Science. https://doi.org/10.1126/science.266.5188.1218
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