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A Neutral Templating Route to Mesoporous Molecular Sieves
Abstract
A neutral templating route for preparing mesoporous molecular sieves is demonstrated based on hydrogen-bonding interactions and self-assembly between neutral primary amine micelles (S°) and neutral inorganic precursors (1°). The S° 1° templating pathway produces ordered mesoporous materials with thicker framework walls, smaller x-ray scattering domain sizes, and substantially improved textural mesoporosities in comparison with M41S materials templated by quaternary ammonium cations of equivalent chain length. This synthetic strategy also allows for the facile, environmentally benign recovery of the cost-intensive template by simple solvent extraction methods. The S° 1° templating route provides for the synthesis of other oxide mesostructures (such as aluminas) that may be less readily accessible by electrostatic templating pathways.
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Cited by
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1998) · Nature · doi:10.1038/24132 · Cited by 2,493
Adsorption — from theory to practice
Dąbrowski, A. (2001) · Advances in Colloid and Interface Science · doi:10.1016/s0001-8686(00)00082-8 · Cited by 2,375
Ordered mesoporous materials in catalysis
Taguchi, A., & Schüth, F. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2004.06.030 · Cited by 2,119
A Review: Fundamental Aspects of Silicate Mesoporous Materials
ALOthman, Z. (2012) · Materials · doi:10.3390/ma5122874 · Cited by 2,084
Mesoporous carbon materials: Synthesis and modification
Liang, C., Li, Z., & Dai, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702046 · Cited by 1,935
Metadata
- Authors
- Tanev, P. T., & Pinnavaia, T. J.
- Venue
- Science
- Published
- 1995-02-10
- Volume
- 267
- Issue
- 5199
- Pages
- 865-867
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2075513979
- Cited by
- 1,787
- References
- 0
- FWCI
- 43.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tanev, P. T., & Pinnavaia, T. J. (1995). A Neutral Templating Route to Mesoporous Molecular Sieves. Science. https://doi.org/10.1126/science.267.5199.865
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